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Author: search.filters.author.Whang, WTSubject: search.filters.subject.photorefractive

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Now showing 1 - 3 of 3
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    Item type:Item,
    The effect of laser wavelength on the photorefractive characteristics of PMDA-DR19 based photorefractive polymeric materials
    (1997-09-01)
    Chang, CJ
    ;
    Wang, HC
    ;
    Liao, GY
    ;
    Whang, WT
    ;
    Liu, JM
    The photoconductivity and photorefractive characteristics of PMDA-DR19-based photoconducting nonlinear optical polymeric films with different compositions were studied using red and green lasers. Contributions of dopants and the host to the photoconductive and photorefractive properties are systematically discussed. The virgin nonlinear optical material PMDA-DR19 was neither photoconductive nor photorefractive in nature. However, it became photoconductive and photorefractive once the charge transport material was incorporated into the PMDA-DR19/PVB polymer film. Films containing more nonlinear optical chromophore exhibited higher diffraction efficiency. Response speed was further elevated when an additional charge generation material was doped in. Diffraction grating was observed under zero electric field and was confirmed due to a photorefractive effect by the two-beam coupling effect. In addition to composition modification, the laser light source was also an important factor in changing the PR response speed. The photorefractive response speed was tremendously improved when films were written and read by two different laser beams, either red/green lasers or green/red lasers. (C) 1997 Elsevier Science Ltd.
  • Thumbnail Image
    Item type:Item,
    Effect of the sensitizer on the properties of fully functionalized photorefractive epoxy polymers and their performance in the hologram image storage
    (1999-06-01)
    Chang, CJ
    ;
    Whang, WT
    ;
    Hsu, KY
    ;
    Hsieh, ML
    ;
    材料科學與工程學系
    The 3-amino-9-ethyl carbazole (AEC)/Dispersed Orange 3 (DO3)/diglycidyl 1,2 cyclohexanedicarboxylate (DCD) main chain copolymers are synthesized and studied on their photorefractive (PR), photoconductive, and holographic characteristics. They are good hologram recording media because not only the stored hologram exhibits excellent fringe contrast with the resolution at about 20 mu m, but also the image can be stored, erased, and overwritten. The UV/Vis spectra shows that AEC segments may form charge transfer complexes with either DO3 segments or TNF sensitizers. By incorporating the sensitizer or increasing the charge transfer component concentration, the grating growth rate can be speeded up. Applying an electric field on the polymer film containing no sensitizer helps to elevate the grating growth speed, but it shows little influence on the grating growth speed of the films with sensitizers. More nonlinear optical (NLO) segments in the copolymer result in higher diffraction efficiency. The dark decay of the film depends on the dark conductivity. Incorporating sensitizers or more charge transport segments leads to more dark decay because of increasing dark conductivity. The dark decay of the PR properties at elevated temperature can also be evaluated by the thermal stimulated discharge current (TSDC) spectroscopy technique. (C) 1999 John Wiley & Sons, Inc.
  • Thumbnail Image
    Item type:Item,
    The effect of laser wavelength on the photorefractive characteristics of PMDA-DR19 based photorefractive polymeric materials
    (1997-09-01)
    Chang, CJ
    ;
    Wang, HC
    ;
    Liao, GY
    ;
    Whang, WT
    ;
    Liu, JM
    The photoconductivity and photorefractive characteristics of PMDA-DR19-based photoconducting nonlinear optical polymeric films with different compositions were studied using red and green lasers. Contributions of dopants and the host to the photoconductive and photorefractive properties are systematically discussed. The virgin nonlinear optical material PMDA-DR19 was neither photoconductive nor photorefractive in nature. However, it became photoconductive and photorefractive once the charge transport material was incorporated into the PMDA-DR19/PVB polymer film. Films containing more nonlinear optical chromophore exhibited higher diffraction efficiency. Response speed was further elevated when an additional charge generation material was doped in. Diffraction grating was observed under zero electric field and was confirmed due to a photorefractive effect by the two-beam coupling effect. In addition to composition modification, the laser light source was also an important factor in changing the PR response speed. The photorefractive response speed was tremendously improved when films were written and read by two different laser beams, either red/green lasers or green/red lasers. (C) 1997 Elsevier Science Ltd.