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收集所有交通大學研究人員與學生個人或團體所發表之各項學術著作，涵蓋期刊論文、教師專書、學位論文等項。;;Collections of Publications of NCTU Researchers and Students Like Journal Papers and Thesis.

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Subject: search.filters.subject.charge extraction

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    Realizing Efficient Charge/Energy Transfer and Charge Extraction in Fullerene-Free Organic Photovoltaics via a Versatile Third Component
    (2019-08-01)
    Cheng, Hao-Wen
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    Zhang, Huotian
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    Lin, Yu-Che
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    She, Nian-Zu
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    Wang, Rui
    Solution-processed organic photovoltaics (OPVs) based on bulk-heterojunctions have gained significant attention to alleviate the increasing demend of fossil fuel in the past two decades. OPVs combined of a wide bandgap polymer donor and a narrow bandgap nonfullerene acceptor show potential to achieve high performance. However, there are still two reasons to limit the OPVs performance. One, although this combination can expand from the ultraviolet to the near-infrared region, the overall external quantum efficiency of the device suffers low values. The other one is the low open-circuit voltage (V-OC) of devices resulting from the relatively downshifted lowest unoccupied molecular orbital (LUMO) of the narrow bandgap. Herein, the approach to select and incorporate a versatile third component into the active layer is reported. A third component with a bandgap larger than that of the acceptor, and absorption spectra and LUMO levels lying within that of the donor and acceptor, is demonstrated to be effective to conquer these issues. As a result, the power conversion efficiencies (PCEs) are enhanced by the elevated short-circuit current and V-OC; the champion PCEs are 11.1% and 13.1% for PTB7-Th:IEICO-4F based and PBDB-T:Y1 based solar cells, respectively.
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    Anomalous Charge-Extraction Behavior for Graphene-Oxide (GO) and Reduced Graphene-Oxide (rGO) Films as Efficient p-Contact Layers for High-Performance Perovskite Solar Cells
    (2018-01-25)
    Jokar, Efat
    ;
    Huang, Zhong Yi
    ;
    Narra, Sudhakar
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    Wang, Chi-Yung
    ;
    Kattoor, Vidya
    Reduced graphene oxides (rGO) are synthesized via reduction of GO with reducing agents as a hole-extraction layer for high-performance inverted planar heterojunction perovskite solar cells. The best efficiencies of power conversion (PCE) of these rGO cells exceed 16%, much greater than those made of GO and poly(3,4-ethenedioxythiophene):poly(styrenesulfonate) films. A flexible rGO device shows PCE 13.8% and maintains 70% of its initial performance over 150 bending cycles. It is found that the hole-extraction period is much smaller for the GO/methylammonium lead-iodide perovskite (PSK) film than for the other rGO/PSK films, which contradicts their device performances. Photoluminescence and transient photoelectric decays are measured and control experiments are performed to prove that the reduction of the oxygen-containing groups in GO significantly decreases the ability of hole extraction from PSK to rGO and also retards the charge recombination at the rGO/PSK interface. When the hole injection from PSK to GO occurs rapidly, hole propagation from GO to the indium-doped tin oxide (ITO) substrate becomes a bottleneck to overcome, which leads to a rapid charge recombination that decreases the performance of the GO device relative to the rGO device.
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    Characterisation of electron transport and charge recombination using temporally resolved and frequency-domain techniques for dye-sensitised solar cells
    (2012)
    Li, Lu-Lin
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    Chang, Yu-Cheng
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    Wu, Hui-Ping
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    Diau, Eric Wei-Guang
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    應用化學系
    We review systematically the kinetic characterisation of electron transport and charge recombination in dye-sensitised solar cells (DSSC) using both temporally resolved and frequency-domain techniques. For the temporally resolved approach, charge extraction (CE), transient-photocurrent decay (TCD) and transient-photovoltage decay (TVD) methods are introduced in detail; for the frequency-domain approach, techniques involving electrochemical impedance spectroscopy (EIS), intensity-modulated photocurrent spectroscopy (IMPS) and intensity-modulated photovoltage spectroscopy (IMVS) are presented in detail. The TCD and TVD data are obtained under short-circuit and open-circuit conditions, respectively, and the electron diffusion coefficients and electron lifetimes are extracted from fitting the decay curves accordingly; the IMPS/IMVS results are the counterparts of the TCD/TVD results in the frequency domain. Even though the EIS results are readily acquired, an accurate interpretation of the data requires an appropriate model to determine the internal features of the device. This review provides an account of each technique about its operating principle, experimental setup and data analysis. As case studies for each technique, examples are given to rationalise the observed potential shift, decay coefficients of electron transport and of charge recombination in relation to the corresponding photovoltaic performance of the device.