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An NMR and XRD study of solidification/stabilization of chromium with portland cement and beta-C2S
(1996-06-01)
Lin, CK
;
Chen, JN
;
Lin, CC
;
環境工程研究所
;
材料科學與工程學系
Solidificalion/stabilization of chromium with Portland cement Type I and P-dicalcium silicate (beta-C2S) was investigated by means of the Si-29 solid stale Magic Angle Spinning/Nuclear Magnetic Resonance (Si-29 MAS/NMR) and X-ray Diffraction (XRD) techniques. It is found that chromium nitrate can increase the extent of beta-C2S hydration. It is also confirmed that the chromium ion is easily incorporated into the beta-C2S paste and hydrated Portland cement, and that it affects the characteristics of hydration and hydration products. Formation of beta-calcium chromium oxide hydrate (beta-CaCrO4 . 2H2(O)) during the hydration of chromium-doped beta-C2S and calcium chromium oxide hydrate (CaCrO4 . 2H(2)O) during the hydration of chromium-doped Portland cement indicates the substitution of chromium for silicon in hydration products. The chromium ion, Cr3+, is thus stabilized and solidified through this mechanism.
Formation of Cr-O and Cr-N-O films serving as Cu oxidation resistant layers and their N-2 pre-sintering effect
(1998-12-14)
Chuang, JC
;
Chen, MC
;
電子工程學系及電子研究所
;
Department of Electronics Engineering and Institute of Electronics
This study investigates the Cu oxidation resistant layers of sputter deposited Cr-O and reactively sputter deposited Cr-N-O of 200 Angstrom thickness. with and without, thermal N-2 pre-sintering treatment. The resistance against Cu oxidation (or the highest annealing temperatures without causing Cu oxidation) of the Cr-O and Cr-N-O covered Cu films were found to be 350 and 500 degrees C, respectively, in an O-2 ambient. The inherent defects in the Cr-O lavers and the nitrogen doping in the Cr-N-O layers were believed to be the principal causes for the distinction of the resistance against Cu oxidation. With Na pre-sintering treatments on the Cr-O or Cr-N-O covered Cu films, the ability of resistance against Cu oxidation was degraded. The higher the N-2 pre-sintering temperature was, the lower the oxidation temperature of Cu became. The N-2 pre-sintering thermal process led to formation of defects on the Cr-O and Cr-N-O layers, resulting in the degradation of the ability of resistance against Cu oxidation. Thus, the application of Cr-O or Cr-N-O as a resistant layer against Cu oxidation should avoid such an excess thermal treatment. (C) 1998 Elsevier Science S.A. All rights reserved.
Reversible Cleavage/Formation of the Chromium-Chromium Quintuple Bond in the Highly Regioselective Alkyne Cyclotrimerization
(2017-11-27)
Huang, Yu-Siang
;
Huang, Gou-Tao
;
Liu, Yao-Lun
;
Yu, Jen-Shiang K.
;
Tsai, Yi-Chou
Herein we report the employment of the quintuply bonded dichromium amidinates [Cr{(2)-HC(N-2,6-(Pr2C6H3)-Pr-i)(N-2,6-R2C6H3)}](2) (R=iPr (1), Me (7)) as catalysts to mediate the [2+2+2] cyclotrimerization of terminal alkynes giving 1,3,5-trisubstituted benzenes. During the catalysis, the ultrashort Cr-Cr quintuple bond underwent reversible cleavage/formation, corroborated by the characterization of two inverted arene sandwich dichromium complexes (-(6):(6)-1,3,5-(Me3Si)(3)C6H3)[Cr{(2)-HC(N-2,6-(Pr2C6H3)-Pr-i)(N-2,6-R2C6H3)}](2) (R=Pr-i (5), Me (8)). In the presence of sigma donors, such as THF and 2,4,6-Me3C6H2CN, the bridging arene 1,3,5-(Me3Si)(3)C6H3 in 5 and 8 was extruded and 1 and 7 were regenerated. Theoretical calculations were employed to disclose the reaction pathways of these highly regioselective [2+2+2] cylcotrimerization reactions of terminal alkynes.
Formation of Cr-O and Cr-N-O films serving as Cu oxidation resistant layers and their N-2 pre-sintering effect
(1998-12-14)
Chuang, JC
;
Chen, MC
;
電子工程學系及電子研究所
;
Department of Electronics Engineering and Institute of Electronics
This study investigates the Cu oxidation resistant layers of sputter deposited Cr-O and reactively sputter deposited Cr-N-O of 200 Angstrom thickness. with and without, thermal N-2 pre-sintering treatment. The resistance against Cu oxidation (or the highest annealing temperatures without causing Cu oxidation) of the Cr-O and Cr-N-O covered Cu films were found to be 350 and 500 degrees C, respectively, in an O-2 ambient. The inherent defects in the Cr-O lavers and the nitrogen doping in the Cr-N-O layers were believed to be the principal causes for the distinction of the resistance against Cu oxidation. With Na pre-sintering treatments on the Cr-O or Cr-N-O covered Cu films, the ability of resistance against Cu oxidation was degraded. The higher the N-2 pre-sintering temperature was, the lower the oxidation temperature of Cu became. The N-2 pre-sintering thermal process led to formation of defects on the Cr-O and Cr-N-O layers, resulting in the degradation of the ability of resistance against Cu oxidation. Thus, the application of Cr-O or Cr-N-O as a resistant layer against Cu oxidation should avoid such an excess thermal treatment. (C) 1998 Elsevier Science S.A. All rights reserved.
Field emission properties of vertically aligned carbon nanotubes grown on bias-enhanced hydrogen plasma-pretreated Cr film
(2003-11-01)
Chen, CF
;
Lin, CL
;
Wang, CM
;
材料科學與工程學系
;
Department of Materials Science and Engineering
Using CH4/H-2 source gases, vertically aligned carbon nanotubes were grown on a Cr film by microwave plasma chemical vapor deposition. The Cr film on a silicon wafer had a constant thickness of 100 nm, and bias-enhanced H, plasma pre-treatment was performed for various periods to modify the surface of the Cr film. Bias voltage of - 150 V was applied during both pre-treatment and growth steps, the resultant carbon nanotubes on a Cr film, which had been pretreated in bias-enhanced H-2 plasma for 5 min were vertically aligned. The field emission properties of the resultant carbon nanotubes included an emission current of 0.305 mA at 2 V/mum; and a turn-on field of 1.7 V/mum. (C) 2003 Elsevier B.V. All rights reserved.
Stepwise Construction of the Cr-Cr Quintuple Bond and Its Destruction upon Axial Coordination
(2012)
Huang, Yu-Lun
;
Lu, Duan-Yen
;
Yu, Hsien-Cheng
;
Yu, Jen-Shiang K.
;
Hsu, Chia-Wei
Quintuply-Bonded Dichromium(I) Complexes Featuring Metal-Metal Bond Lengths of 1.74 angstrom
(2008)
Hsu, Chia-Wei
;
Yu, Jen-Shiang K.
;
Yen, Chun-Hsu
;
Lee, Gene-Hsiang
;
Wang, Yu
Remarkably short metal-metal bonds: A lantern-type quintuply bonded Dichromium(I) complex
(2008)
Tsai, Yi-Chou
;
Hsu, Chia-Wei
;
Yu, Jen-Shiang K.
;
Lee, Gene-Hsiang
;
Wang, Yu
An NMR and XRD study of solidification/stabilization of chromium with portland cement and beta-C2S
(1996-06-01)
Lin, CK
;
Chen, JN
;
Lin, CC
;
環境工程研究所
;
材料科學與工程學系
Solidificalion/stabilization of chromium with Portland cement Type I and P-dicalcium silicate (beta-C2S) was investigated by means of the Si-29 solid stale Magic Angle Spinning/Nuclear Magnetic Resonance (Si-29 MAS/NMR) and X-ray Diffraction (XRD) techniques. It is found that chromium nitrate can increase the extent of beta-C2S hydration. It is also confirmed that the chromium ion is easily incorporated into the beta-C2S paste and hydrated Portland cement, and that it affects the characteristics of hydration and hydration products. Formation of beta-calcium chromium oxide hydrate (beta-CaCrO4 . 2H2(O)) during the hydration of chromium-doped beta-C2S and calcium chromium oxide hydrate (CaCrO4 . 2H(2)O) during the hydration of chromium-doped Portland cement indicates the substitution of chromium for silicon in hydration products. The chromium ion, Cr3+, is thus stabilized and solidified through this mechanism.
An NMR, XRD and EDS study of solidification/stabilization of chromium with portland cement and C3S
(1997-09-01)
Lin, CK
;
Chen, JN
;
Lin, CC
;
環境工程研究所
;
材料科學與工程學系
Solidification/stabilization (S/S) of chromium with Portland cement type I and tricalcium silicate (C3S) was investigated by using the Si-29 solid state magic angle spinning/nuclear magnetic resonance (Si-29 MAS/NMR), X-ray diffraction (XRD) and energy dispersive spectroscopy (EDS). The present study confirms that chromium nitrate can increase the extent of C3S hydration. It also confirms that the chromium ion is easily incorporated into the C3S paste and hydrated Portland cement, and that it affects the characteristics of the hydration processes and their hydration products, The formation of calcium chromium silicate (CaCrSi4O10), calcium chromium oxide hydrate (CaCrO4 . 2H(2)O), and calcium dichromate (CaCr2O7) during the hydration of chromium-doped C3S indicates the probable substitution of chromium for silicon in the calcium silicate hydrate (C-S-H) and the interaction between Cr and Si. Furthermore, formation of CaCrSi4O10, aluminum chromium oxide hydroxide hydrate (Al(OH)CrO4 . H2O), aluminum chromium oxide hydroxide (Al-2(OH)(4)CrO4), and CaCr2O7 during the hydration of chromium-doped cement reveals not only the probable substitution of chromium for silicon in the calcium silicate hydrate (C-S-H) but also the interaction among Cr, Si and Al, Apparently, the chromium iron (Cr3+) may also be stabilized and solidified through these mechanisms in addition to those proposed by other investigators. (C) 1997 Elsevier Science B.V.

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