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Item type:Item, Nucleophilic Conjugate 1,5-Addition of Gilman Reagents to (E)-Hex-2-en-4-ynedioates: An Access to ()-Substituted Muconates(2015-08-01) ;Tai, Hung-Che ;Chavan, Arjun S. ;Chuang, Shih-Ching ;應用化學系Department of Applied ChemistryAn unusual nucleophilic conjugate addition of organocuprates to enynedioates resulted in chemo- and regioselective formation of ()-addition products, rather than ()-addition products, in moderate to good yields. This addition pattern is different from that with organophosphanes or alkyl amines, and presents a short and efficient method for the preparation of various ()-alkyl- or -aryl-substituted muconates compared with other synthetic approaches.Item type:Item, The electronic structure change induced by stripe phase formation in cuprates(2004-08-01) ;Lin, JY ;Huang, CW ;Lin, PH ;Sun, CPLee, JMIt has been suggested that the stripe phase shows ID charge transport in the CuO2 planes instead of the 2D characteristics of the Zhang-Rice band. X-ray absorption near edge spectroscopy (XANES) has been used to study the electronic structure of the stripe phase compounds La2-xSrxCuO4, and La2-x-yNdySrxCuO4 for x around 1/8. The measurements were performed at both 300 and 28 K to examine the possible electronic structure change above and below the temperature of the stripe phase formation. (C) 2004 Elsevier B.V. All rights reserved.