標題: Experimental and theoretical investigation of high-power laser ionization and dissociation of methane
作者: Sharifi, A.
Kong, F.
Chin, S. L.
Mineo, H.
Dyakov, Y.
Mebel, A. M.
Chao, S. D.
Hayashi, M.
Lin, S. H.
應用化學系
Department of Applied Chemistry
公開日期: 27-Sep-2007
摘要: The main purpose of this paper is to report the high-power laser ionization-dissociation of CH4 at various femtosecond (fs) laser intensities (from 1 x 10 14 W/cm(2) to 2 x 1015 W/cm(2)) with a laser pulse duration of 48 fs. The generalized molecular Keldysh theory has been applied to calculate the ionization yields for CH4+ and CH4++. Outside the influence of the A intense laser, we propose to calculate the mass spectra due to the decomposition of CH4+ and CH4++, using the Rice-Ramsperger-Kassel-Marcus (RRKM) theory. The agreement between the experimental mass spectra and calculated mass spectra seems to be reasonable.
URI: http://dx.doi.org/10.1021/jp074053f
http://hdl.handle.net/11536/10308
ISSN: 1089-5639
DOI: 10.1021/jp074053f
期刊: JOURNAL OF PHYSICAL CHEMISTRY A
Volume: 111
Issue: 38
起始頁: 9405
結束頁: 9416
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