完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.author | Chan, Shih-Chi | en_US |
dc.contributor.author | Kuo, Shiao-Wei | en_US |
dc.contributor.author | Lu, Chu-Hua | en_US |
dc.contributor.author | Lee, Hsin-Fang | en_US |
dc.contributor.author | Chang, Feng-Chih | en_US |
dc.date.accessioned | 2014-12-08T15:13:31Z | - |
dc.date.available | 2014-12-08T15:13:31Z | - |
dc.date.issued | 2007-08-10 | en_US |
dc.identifier.issn | 0032-3861 | en_US |
dc.identifier.uri | http://dx.doi.org/10.1016/j.polymer.2007.06.053 | en_US |
dc.identifier.uri | http://hdl.handle.net/11536/10448 | - |
dc.description.abstract | A series of semicrystalline diblock copolymers of poly(4-vinylpyridine-b-epsilon-caprolactone) (P4VP-b-PCL) have been synthesized by the living ROP of CL followed by the TEMPO polymerization of 4-VP. Depending on the relative block length and different solvent compositions, these copolymers self-assemble into different supramolecular structures in toluene/dichloromethane (DCM) solution, including spherical micelles, bowl-shaped vesicles, multilayer vesicles, porous spheres, and large compound micelles. In methanol/DCM solution system, the crystalline PCL core disturbs the balance of free energy, thus results in a series of morphological changes including spherical micelles, worm-like rods, vesicles, coexisted vesicles and lamella, and finally platelet lamella. (c) 2007 Elsevier Ltd. All rights reserved. | en_US |
dc.language.iso | en_US | en_US |
dc.subject | block copolymer | en_US |
dc.subject | TEMPO | en_US |
dc.subject | self-assembly | en_US |
dc.title | Syntheses and characterizations of the multiple morphologies formed by the self-assembly of the sernicrystalline P4VP-b-PCL diblock copolymers | en_US |
dc.type | Article | en_US |
dc.identifier.doi | 10.1016/j.polymer.2007.06.053 | en_US |
dc.identifier.journal | POLYMER | en_US |
dc.citation.volume | 48 | en_US |
dc.citation.issue | 17 | en_US |
dc.citation.spage | 5059 | en_US |
dc.citation.epage | 5068 | en_US |
dc.contributor.department | 應用化學系 | zh_TW |
dc.contributor.department | Department of Applied Chemistry | en_US |
dc.identifier.wosnumber | WOS:000249085000019 | - |
dc.citation.woscount | 32 | - |
顯示於類別: | 期刊論文 |