White light generation under violet-blue excitation from tunable green-to-red emitting Ca2MgSi2O7 : Eu,Mn through energy transfer

Abstract

Yellowish green-to-orange red emission can be generated by energy transfer from Eu2+ to Mn2+ in the Ca2MgSi2O7 host matrix. Eu2+-doped Ca2MgSi2O7 shows a broad green emission band centering at 528 nm and Mn2+-doped Ca2MgSi2O7 exhibits a red emission at around 602 nm. The authors have demonstrated that the mechanism of energy transfer from Eu2+ to Mn2+ in Ca2MgSi2O7:Eu,Mn phosphor is a resonant type via a dipole-quadrupole mechanism. They have also shown that the white light with varied hue, depending on contents of Mn2+, is generated by combination of predesigned emission wavelength-tunable Ca2MgSi2O7:Eu,Mn phosphors and violet-blue light source. (c) 2007 American Institute of Physics.