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dc.contributor.authorHuang, Chih-Haoen_US
dc.contributor.authorChang, Yu-Hsuen_US
dc.contributor.authorWang, Hsiao-Wanen_US
dc.contributor.authorCheng, Soofinen_US
dc.contributor.authorLee, Chi-Youngen_US
dc.contributor.authorChiu, Hsin-Tienen_US
dc.date.accessioned2014-12-08T15:16:21Z-
dc.date.available2014-12-08T15:16:21Z-
dc.date.issued2006-06-22en_US
dc.identifier.issn1520-6106en_US
dc.identifier.urihttp://dx.doi.org/10.1021/jp0618835en_US
dc.identifier.urihttp://hdl.handle.net/11536/12137-
dc.description.abstractPorous carbon materials with pore sizes from 3 to 200 nm were synthesized by reacting hexafluorobenzene with Na liquid at 623 K. NaF crystals, a byproduct formed in the reaction, acted as nanotemplate to assist the pore formation. By employing hexafluorobenzene to react with Na incorporated within the channels ( diameter 200 nm) of anodized aluminum oxide ( AAO) membranes at 323- 623 K, the carbon material can be fabricated into aligned porous nanotube arrays ( ca. 250 nm in diameter, ca. 20 nm in wall thickness, ca. 0.06 mm in length, and ca. 3-90 nm in pore diameter). These materials were characterized by X-ray diffraction, scanning and transmission electron microscopy, X-ray energy dispersive spectroscopy, electron diffraction, thermal gravimetric analysis, and nitrogen physical adsorption experiments.en_US
dc.language.isoen_USen_US
dc.titleFormation of porous carbon materials with in situ generated NaF nanotemplateen_US
dc.typeArticleen_US
dc.identifier.doi10.1021/jp0618835en_US
dc.identifier.journalJOURNAL OF PHYSICAL CHEMISTRY Ben_US
dc.citation.volume110en_US
dc.citation.issue24en_US
dc.citation.spage11818en_US
dc.citation.epage11822en_US
dc.contributor.department應用化學系zh_TW
dc.contributor.departmentDepartment of Applied Chemistryen_US
dc.identifier.wosnumberWOS:000238284600032-
dc.citation.woscount5-
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