Dissociation of energy-selected c-C3H6S+ studied with threshold photoelectron-photolon coincidence experiments and calculations

doi:10.1016/j.cplett.2006.03.020

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DC 欄位	值	語言
dc.contributor.author	Chiang, SY	en_US
dc.contributor.author	Fang, YS	en_US
dc.contributor.author	Lin, CN	en_US
dc.date.accessioned	2014-12-08T15:16:36Z	-
dc.date.available	2014-12-08T15:16:36Z	-
dc.date.issued	2006-05-10	en_US
dc.identifier.issn	0009-2614	en_US
dc.identifier.uri	http://dx.doi.org/10.1016/j.cplett.2006.03.020	en_US
dc.identifier.uri	http://hdl.handle.net/11536/12259	-
dc.description.abstract	The dissociation of energy-selected c-C3H6S+ was investigated in a region 10.2-10.9 eV with a threshold photoelectron-photoion coincidence technique. Branching ratios and average releases of kinetic energy for channel c-C3H6S+ -> H2CS+ + C2H4 were derived from coincidence mass spectra. The measured small releases of kinetic energy near the appearance onset agree with statistical calculations; a linearly extrapolated threshold at 10.39 +/- 0.01 eV agrees with a predicted energy 10.35 eV with the GAUSSIAN-3 method. We discuss plausible mechanisms for c-C3H6S+ dissociating to CH3CS+ + CH3 based on G3B3 calculations to rationalize the absence of CH3CS+ signal in these experiments. (c) 2006 Elsevier B.V. All rights reserved.	en_US
dc.language.iso	en_US	en_US
dc.title	Dissociation of energy-selected c-C3H6S+ studied with threshold photoelectron-photolon coincidence experiments and calculations	en_US
dc.type	Article	en_US
dc.identifier.doi	10.1016/j.cplett.2006.03.020	en_US
dc.identifier.journal	CHEMICAL PHYSICS LETTERS	en_US
dc.citation.volume	422	en_US
dc.citation.issue	4-6	en_US
dc.citation.spage	475	en_US
dc.citation.epage	480	en_US
dc.contributor.department	應用化學系	zh_TW
dc.contributor.department	Department of Applied Chemistry	en_US
dc.identifier.wosnumber	WOS:000237840200036	-
dc.citation.woscount	0	-
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