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dc.contributor.authorHsu, Yu-Chenen_US
dc.contributor.authorShen, Jiun-Shianen_US
dc.contributor.authorLin, Bo-Chaoen_US
dc.contributor.authorChen, Wen-Chingen_US
dc.contributor.authorChan, Yi-Tsuen_US
dc.contributor.authorChing, Wei-Minen_US
dc.contributor.authorYap, Glenn P. A.en_US
dc.contributor.authorHsu, Chao-Pingen_US
dc.contributor.authorOng, Tiow-Ganen_US
dc.date.accessioned2015-07-21T08:29:10Z-
dc.date.available2015-07-21T08:29:10Z-
dc.date.issued2015-02-16en_US
dc.identifier.issn1433-7851en_US
dc.identifier.urihttp://dx.doi.org/10.1002/anie.201406481en_US
dc.identifier.urihttp://hdl.handle.net/11536/124322-
dc.description.abstractThe simple synthetic development of acyclic pincer bis(pyridine)carbodicarbene is depicted herein. Presented is the first isolated structural pincer carbodicarbene with a C-C-C angle of 143 degrees, larger than the monodentate framework. More importantly, theoretical analysis showed that this carbodicarbene embodies a more allene-like character. Palladium complexes supported by this pincer ligand are active catalysts for Heck-Mizoroki and Suzuki-Miyaura coupling reactions.en_US
dc.language.isoen_USen_US
dc.subjectcarbenesen_US
dc.subjectcarbodicarbenesen_US
dc.subjectCC couplingen_US
dc.subjectligand designen_US
dc.subjectpalladiumen_US
dc.titleSynthesis and Isolation of an Acyclic Tridentate Bis(pyridine)carbodicarbene and Studies on Its Structural Implications and Reactivitiesen_US
dc.typeArticleen_US
dc.identifier.doi10.1002/anie.201406481en_US
dc.identifier.journalANGEWANDTE CHEMIE-INTERNATIONAL EDITIONen_US
dc.citation.volume54en_US
dc.citation.spage2420en_US
dc.citation.epage2424en_US
dc.contributor.department應用化學系zh_TW
dc.contributor.departmentDepartment of Applied Chemistryen_US
dc.identifier.wosnumberWOS:000350100000020en_US
dc.citation.woscount1en_US
Appears in Collections:Articles