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dc.contributor.authorWu, Kuan-Yien_US
dc.contributor.authorChiu, Chun-Chiehen_US
dc.contributor.authorChuang, Wei-Tsungen_US
dc.contributor.authorWang, Chien-Lungen_US
dc.contributor.authorHsu, Chain-Shuen_US
dc.date.accessioned2015-07-21T08:28:32Z-
dc.date.available2015-07-21T08:28:32Z-
dc.date.issued2015-01-01en_US
dc.identifier.issn1759-9954en_US
dc.identifier.urihttp://dx.doi.org/10.1039/c4py01361aen_US
dc.identifier.urihttp://hdl.handle.net/11536/124394-
dc.description.abstractA series of three PVTh4FBT polymers containing different alkyl side chain placement was synthesized. The thermochromic behaviors and DFT calculations indicated that the backbone coplanarity and rigidity of the PVTh4FBT polymers can be effectively modulated by adjusting the side chain position and density. Higher ordered and better oriented edge-on lamellar packing was formed by P1, which possesses the most rigid backbone among the three polymers and pre-aggregates in the solution. P1 also delivered the highest hole mobility (0.26 cm(2) V-1 s(-1)) among the three analogues because its thin-film morphology is in favor of charge transport.en_US
dc.language.isoen_USen_US
dc.titleThe backbone rigidity and its influence on the morphology and charge mobility of FBT based conjugated polymersen_US
dc.typeArticleen_US
dc.identifier.doi10.1039/c4py01361aen_US
dc.identifier.journalPOLYMER CHEMISTRYen_US
dc.citation.spage1309en_US
dc.citation.epage1315en_US
dc.contributor.department應用化學系zh_TW
dc.contributor.departmentDepartment of Applied Chemistryen_US
dc.identifier.wosnumberWOS:000349666600011en_US
dc.citation.woscount0en_US
Appears in Collections:Articles