標題: | Effect of the transition metal on the synthesis of quaternary sulfides MPb8In17S34 (M = Cu, Ag, Au) |
作者: | Wang, KC Lee, CS 應用化學系 Department of Applied Chemistry |
公開日期: | 20-二月-2006 |
摘要: | Quaternary sulfides MPb8In17S34 (M = Cu, Ag, Au) were synthesized at 1123 K from their elements in stoichiometric ratios. These compounds crystallize in monoclinic space group P2(1)/m. The crystal structures feature combinations of (2)(infinity)[InS2] (NaCl111-type) and (2)(infinity)[MPb2In3S6] (NaCl100-type) slabs. These compounds are semiconductors with band gaps near 1.3 eV. |
URI: | http://dx.doi.org/10.1021/ic051447h http://hdl.handle.net/11536/12619 |
ISSN: | 0020-1669 |
DOI: | 10.1021/ic051447h |
期刊: | INORGANIC CHEMISTRY |
Volume: | 45 |
Issue: | 4 |
起始頁: | 1415 |
結束頁: | 1417 |
顯示於類別: | 期刊論文 |