標題: Synthesis of tetraacetal pentaoxa-cages and convex oxa-cages by ozonolysis of 7-oxabicyclo[2.2.1]heptenes
作者: Lin, CC
Wu, HJ
應用化學系
Department of Applied Chemistry
關鍵字: tetraacetal pentaoxa-cages;convex oxa-cages;ozonolysis,;7-oxabicyclo[2.2.1]heptenes
公開日期: 1-Jun-1996
摘要: Tetraacetal pentaoxa-cage compounds 4a and 4b and convex oxa-cage compounds 6, 7 and 8 are synthesized from alkylfurans in three steps. Ozonolysis of the endo adducts 2a and 2b in dichloromethane at - 78 degrees C followed by reduction with dimethyl sulfide gave the tetraacetal pentaoxa-cages 4a and 4b in 85-90% yields, respectively. Ozonolysis of 2a and 2b in dichloromethane at - 78 degrees C followed by treatment with triethylamine gave the convex era-cages 6, 7 and 8 in 85-90% yields, respectively. The synthesis of the tetraacetal pentaoxa-cage 12, possessing aromatic substituents directly on the skeleton of the era-cages, has also been accomplished.
URI: http://hdl.handle.net/11536/1263
ISSN: 0039-7881
期刊: SYNTHESIS-STUTTGART
Volume: 
Issue: 6
起始頁: 715
結束頁: &
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