膦媒介烯炔酯與碳簇之反應

Abstract

本篇論文主要是探討烯炔類化合物與三級膦的反應，發現只使用催化量的三級膦進行反應即可得到產物，觀察碳六十在三級膦催化下與烯炔化合物反應狀況。在尋找最佳化條件後利用一系列烯炔化合物與碳六十反應來探討產率和產物構變化，經由光譜分析、X光單晶繞射驗證產物結構，得知碳六十衍生物立體結構後，便可推斷可能反應機制。

This thesis explores the reactivity of tertiary phosphorous with enyne compounds. Product formation is observed with catalytic amount of tertiary phosphorous added when reacting fullerenes with enyne moieties. Under optimized conditions, a series of enyne are used to explore the reactivity and structural changes when reacting with fullerenes. UV-vis spectroscopy and single crystal X-ray diffraction are used to determine the product structures. Reaction mechanisms are proposed by identifying the structure of fullerene procducts.