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dc.contributor.authorChen, KBen_US
dc.contributor.authorLi, HCen_US
dc.contributor.authorChen, CKen_US
dc.contributor.authorYang, SHen_US
dc.contributor.authorHsieh, BRen_US
dc.contributor.authorHsu, CSen_US
dc.date.accessioned2014-12-08T15:18:12Z-
dc.date.available2014-12-08T15:18:12Z-
dc.date.issued2005-10-18en_US
dc.identifier.issn0024-9297en_US
dc.identifier.urihttp://dx.doi.org/10.1021/ma0513822en_US
dc.identifier.urihttp://hdl.handle.net/11536/13161-
dc.description.abstractTwo series of poly(2,3-Biphenyl-1,4-phenylenevinylene) (DP-PPV) derivatives containing long branched alkoxy chains or fluorenyl substituents were synthesized. The branched alkoxy groups were introduced to enhance the solubility for spin-coating processes. Bulky fluorenyl groups with two hexyl chains on the 9-position were introduced to increase steric hindrance and prevent close packing of the main chain. By controlling the feed ratio of different monomers during polymerization, DP-PPV derivatives with high molecular weights were obtained. All synthesized polymers possess high glass transitions temperatures and thermal stabilities. The maximum photoluminescent emissions of the thin films are located between 498 and 564 nm. Cyclic voltammetric analysis reveals that the band gaps of these light-emitting materials are in the range from 2.4 to 2.5 eV. A double-layer electroluminescent device with the configuration of ITO/PEDOT/polymer 2/Ca/Al exhibited a low turn-on voltage (4.0 V), a very high external quantum efficiency (3.39 cd/A), and a high brightness (16 910 cd/m(2)).en_US
dc.language.isoen_USen_US
dc.titleNovel poly(2,3-biphenyl-1,4-phenylenevinylene) derivatives containing long branched alkoxy and fluorenyl substituents: Synthesis, characterization, and their applications for polymer light-emitting diodesen_US
dc.typeArticleen_US
dc.identifier.doi10.1021/ma0513822en_US
dc.identifier.journalMACROMOLECULESen_US
dc.citation.volume38en_US
dc.citation.issue21en_US
dc.citation.spage8617en_US
dc.citation.epage8624en_US
dc.contributor.department應用化學系zh_TW
dc.contributor.departmentDepartment of Applied Chemistryen_US
dc.identifier.wosnumberWOS:000232564800004-
dc.citation.woscount26-
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