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dc.contributor.authorNakajima, Masakazuen_US
dc.contributor.authorEndo, Yasukien_US
dc.date.accessioned2017-04-21T06:56:41Z-
dc.date.available2017-04-21T06:56:41Z-
dc.date.issued2016-12-28en_US
dc.identifier.issn0021-9606en_US
dc.identifier.urihttp://dx.doi.org/10.1063/1.4973014en_US
dc.identifier.urihttp://hdl.handle.net/11536/133071-
dc.description.abstractPure rotational transitions of the dimethyl-substituted Criegee intermediate (dimethyl carbonyl oxide, acetone oxide), (CH3)(2)COO, were observed in the discharge plasma of a C(CH3)(2)I-2/O-2 gas mixture by Fourier-transform microwave spectroscopy. The observed spectra show small splittings due to the internal rotations of the two methyl groups. Precise rotational constants of the molecule and the barrier heights of the methyl internal rotations were experimentally determined. Published by AIP Publishing.en_US
dc.language.isoen_USen_US
dc.titleFourier-transform microwave spectroscopy of dimethyl-substituted Criegee intermediate (CH3)(2)COOen_US
dc.identifier.doi10.1063/1.4973014en_US
dc.identifier.journalJOURNAL OF CHEMICAL PHYSICSen_US
dc.citation.volume145en_US
dc.citation.issue24en_US
dc.contributor.department應用化學系zh_TW
dc.contributor.departmentDepartment of Applied Chemistryen_US
dc.identifier.wosnumberWOS:000392174800024en_US
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