標題: | Influence of amino acid side chains on the formation of two component self-assembling nanofibrous hydrogels |
作者: | Nelli, Srinivasa Rao Lin, Jhong-Hua Thi Ngoc Anh Nguyen Tseng, Dion Tzu-Huan Talloj, Satish Kumar Lin, Hsin-Chieh 材料科學與工程學系 Department of Materials Science and Engineering |
公開日期: | 2017 |
摘要: | Herein, we report the synthesis and optimization of an aqueous phase two-component co-assembled nanofibrous hydrogel based on charge-transfer (CT) between pyrenebutyric acid and naphthalene diimide-capped groups. This donor-acceptor CT interaction is a powerful driving force that can induce self-assembly in the aqueous phase even if the molecule contains only a single amino acid. The intermolecular CT interactions for mixed components can also be visualized in the quantum-chemical approach. This two-component supramolecular co-assembly provides a new path for the design of self-assembled nanomaterials. |
URI: | http://dx.doi.org/10.1039/c6nj02820a http://hdl.handle.net/11536/133233 |
ISSN: | 1144-0546 |
DOI: | 10.1039/c6nj02820a |
期刊: | NEW JOURNAL OF CHEMISTRY |
Volume: | 41 |
Issue: | 3 |
起始頁: | 1229 |
結束頁: | 1234 |
顯示於類別: | 期刊論文 |