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dc.contributor.authorChu, Chien-Weien_US
dc.contributor.authorJeng, Kai-Shengen_US
dc.contributor.authorChi, Mu-Huanen_US
dc.contributor.authorTsai, Chia-Chanen_US
dc.contributor.authorCheng, Ming-Hsiangen_US
dc.contributor.authorChen, Jiun-Taien_US
dc.date.accessioned2017-04-21T06:55:19Z-
dc.date.available2017-04-21T06:55:19Z-
dc.date.issued2016-09en_US
dc.identifier.issn1022-1352en_US
dc.identifier.urihttp://hdl.handle.net/11536/134267-
dc.description.abstractAlthough many fabrication methods of conjugated polymer nanostructures have been developed, the effects of confinement on the morphologies, chain conformations, and optical properties of conjugated polymers are still not well understood. In this work, poly(9,9-di-n-octylfluorene-alt-benzothiadiazole) (F8BT), a light-emitting conjugated polymer, is used to fabricate nanotubes by a solution wetting method using anodic aluminum oxide templates. The property changes under the nanoscale confinement have been investigated. The morphologies of F8BT nanostructures are characterized by scanning electron microscope, transmission electron microscope, and laser scanning confocal microscope. The data show the hollow morphologies and no or low crystallinity of the nanostructures. The optical properties are also measured using UV-vis absorption, photoluminescence, and confocal Raman spectroscopy. The spectroscopy data indicate that F8BT polymer chains have less intermolecular interactions and coplanarity under the confinement effect.en_US
dc.language.isoen_USen_US
dc.subjectanodic aluminum oxideen_US
dc.subjectconjugated polymersen_US
dc.subjectnanotubesen_US
dc.subjectphotoluminescenceen_US
dc.subjectpoly(9,9-di-n-octylfluorene-alt-benzothiadiazole)en_US
dc.titleConfinement Effects on the Optical Properties and Chain Conformations of Poly(9,9-di-n-octylfluorene-alt-benzothiadiazole) Nanotubesen_US
dc.identifier.journalMACROMOLECULAR CHEMISTRY AND PHYSICSen_US
dc.citation.volume217en_US
dc.citation.issue18en_US
dc.citation.spage2074en_US
dc.citation.epage2080en_US
dc.contributor.department應用化學系zh_TW
dc.contributor.departmentDepartment of Applied Chemistryen_US
dc.identifier.wosnumberWOS:000383886300010en_US
Appears in Collections:Articles