標題: Synthesis of novel triacetal trioxa-cage compounds by ozonolysis of bicyclo[2.2.1]heptenes and bicyclo[2.2.2]octenes
作者: Wu, CY
Lin, CC
Lai, MC
Wu, HJ
交大名義發表
應用化學系
National Chiao Tung University
Department of Applied Chemistry
公開日期: 1-四月-1996
摘要: Several novel triacetal trioxa-cage compounds 11a-11g, 13, 15, 17 and 19 are synthesized in a short sequence. Ozonolysis of bicyclo[2.2.1]heptenes 4a-4c, 8a-8c, 10a, 10b and 14 in dichloromethane at -78 degrees C followed by reduction with dimethyl sulfide gave triacetal era-cages 11a-11g, 13 and 15 in moderate yields, respectively. Ozonolysis of bicycle[2.2.2] octenes 16 and 18 under the same reaction conditions gave triacetal era-cages 17 and 19 in moderate yields, respectively.
URI: http://hdl.handle.net/11536/1383
ISSN: 0009-4536
期刊: JOURNAL OF THE CHINESE CHEMICAL SOCIETY
Volume: 43
Issue: 2
起始頁: 187
結束頁: 194
顯示於類別:期刊論文