標題: | Synthesis of novel triacetal trioxa-cage compounds by ozonolysis of bicyclo[2.2.1]heptenes and bicyclo[2.2.2]octenes |
作者: | Wu, CY Lin, CC Lai, MC Wu, HJ 交大名義發表 應用化學系 National Chiao Tung University Department of Applied Chemistry |
公開日期: | 1-四月-1996 |
摘要: | Several novel triacetal trioxa-cage compounds 11a-11g, 13, 15, 17 and 19 are synthesized in a short sequence. Ozonolysis of bicyclo[2.2.1]heptenes 4a-4c, 8a-8c, 10a, 10b and 14 in dichloromethane at -78 degrees C followed by reduction with dimethyl sulfide gave triacetal era-cages 11a-11g, 13 and 15 in moderate yields, respectively. Ozonolysis of bicycle[2.2.2] octenes 16 and 18 under the same reaction conditions gave triacetal era-cages 17 and 19 in moderate yields, respectively. |
URI: | http://hdl.handle.net/11536/1383 |
ISSN: | 0009-4536 |
期刊: | JOURNAL OF THE CHINESE CHEMICAL SOCIETY |
Volume: | 43 |
Issue: | 2 |
起始頁: | 187 |
結束頁: | 194 |
顯示於類別: | 期刊論文 |