标题: Carbodicarbenes or Bent Allenes
作者: Wang, Ting-Hsuan
Chen, Wen-Ching
Ong, Tiow-Gan
应用化学系
Department of Applied Chemistry
关键字: Carbodicarbene;Bent allene;Carbone;N-Heterocyclic carbenes;N-Hetereocyclic olefin
公开日期: 1-二月-2017
摘要: The pursuit of unusual bonding environments of carbon species with non-octet electronic configurations has been quite active in fundamental organic and theoretical chemistry for many decades. In this respect, a distinct carbone species has been successfully isolated recently and defined as "carbodicarbene" or "bent allene." This neutral two-coordinated central carbon atom possesses two electron lone pairs, while its octet deficiency is overcome by sigma donation of N-heterocyclic carbenes (NHCs) bound to the central carbon. The present review is focused on the rich chemistry of carbodicarbenes in the aspects of synthesis, characterization, and ligand science of metal complex as well as their intrinsic reactivities.
URI: http://dx.doi.org/10.1002/jccs.201600241
http://hdl.handle.net/11536/143843
ISSN: 0009-4536
DOI: 10.1002/jccs.201600241
期刊: JOURNAL OF THE CHINESE CHEMICAL SOCIETY
Volume: 64
起始页: 124
结束页: 132
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