完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.author | Kippo, Takashi | en_US |
dc.contributor.author | Hamaoka, Kanako | en_US |
dc.contributor.author | Ueda, Mitsuhiro | en_US |
dc.contributor.author | Fukuyama, Takahide | en_US |
dc.contributor.author | Ryu, Ilhyong | en_US |
dc.date.accessioned | 2018-08-21T05:52:44Z | - |
dc.date.available | 2018-08-21T05:52:44Z | - |
dc.date.issued | 2017-10-06 | en_US |
dc.identifier.issn | 1523-7060 | en_US |
dc.identifier.uri | http://dx.doi.org/10.1021/acs.orglett.7b02471 | en_US |
dc.identifier.uri | http://hdl.handle.net/11536/143913 | - |
dc.description.abstract | A radical-chain addition of allyl bromides to aryl alkenes, vinyl ester, and vinyl phthalimide was studied in which elusive beta-bromodkyl radicals were trapped efficiently to give 5-bromo-1-pentenes in good to high yields (16 examples). A subsequent carbonylative radical cyclization with AIBN/Bu3SnH/CO was successful in giving the corresponding 3,5-disubstituted cyclohexanone derivatives in moderate yields. Synthesis of a piperidine ring was also successful by subsequent reaction with primary amine. | en_US |
dc.language.iso | en_US | en_US |
dc.title | Bromoallylation of Alkenes Leading to 4-Alkenyl Bromides Based on Trapping of beta-Bromoalkyl Radicals | en_US |
dc.type | Article | en_US |
dc.identifier.doi | 10.1021/acs.orglett.7b02471 | en_US |
dc.identifier.journal | ORGANIC LETTERS | en_US |
dc.citation.volume | 19 | en_US |
dc.citation.spage | 5198 | en_US |
dc.citation.epage | 5200 | en_US |
dc.contributor.department | 應用化學系 | zh_TW |
dc.contributor.department | Department of Applied Chemistry | en_US |
dc.identifier.wosnumber | WOS:000412789600049 | en_US |
顯示於類別: | 期刊論文 |