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dc.contributor.authorKippo, Takashien_US
dc.contributor.authorHamaoka, Kanakoen_US
dc.contributor.authorUeda, Mitsuhiroen_US
dc.contributor.authorFukuyama, Takahideen_US
dc.contributor.authorRyu, Ilhyongen_US
dc.date.accessioned2018-08-21T05:52:44Z-
dc.date.available2018-08-21T05:52:44Z-
dc.date.issued2017-10-06en_US
dc.identifier.issn1523-7060en_US
dc.identifier.urihttp://dx.doi.org/10.1021/acs.orglett.7b02471en_US
dc.identifier.urihttp://hdl.handle.net/11536/143913-
dc.description.abstractA radical-chain addition of allyl bromides to aryl alkenes, vinyl ester, and vinyl phthalimide was studied in which elusive beta-bromodkyl radicals were trapped efficiently to give 5-bromo-1-pentenes in good to high yields (16 examples). A subsequent carbonylative radical cyclization with AIBN/Bu3SnH/CO was successful in giving the corresponding 3,5-disubstituted cyclohexanone derivatives in moderate yields. Synthesis of a piperidine ring was also successful by subsequent reaction with primary amine.en_US
dc.language.isoen_USen_US
dc.titleBromoallylation of Alkenes Leading to 4-Alkenyl Bromides Based on Trapping of beta-Bromoalkyl Radicalsen_US
dc.typeArticleen_US
dc.identifier.doi10.1021/acs.orglett.7b02471en_US
dc.identifier.journalORGANIC LETTERSen_US
dc.citation.volume19en_US
dc.citation.spage5198en_US
dc.citation.epage5200en_US
dc.contributor.department應用化學系zh_TW
dc.contributor.departmentDepartment of Applied Chemistryen_US
dc.identifier.wosnumberWOS:000412789600049en_US
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