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dc.contributor.authorCao, Fong-Yien_US
dc.contributor.authorChen, Yung-Lungen_US
dc.contributor.authorLai, Yu-Yingen_US
dc.contributor.authorCheng, Yen-Juen_US
dc.date.accessioned2018-08-21T05:53:14Z-
dc.date.available2018-08-21T05:53:14Z-
dc.date.issued2018-01-01en_US
dc.identifier.issn0009-4536en_US
dc.identifier.urihttp://dx.doi.org/10.1002/jccs.201700221en_US
dc.identifier.urihttp://hdl.handle.net/11536/144438-
dc.description.abstractA new two-dimensional tetrathienyl-TBDT (TBDT-4T) was synthesized by employing palladium-catalyzed C-H benzannulation between an iodobiaryl and 1,2-dithienylacetylene. The stannylated TBDT-4T was copolymerized with di(thiophenyl)difluorobenzothiadiazole (FBT) and fluorothienothiophene (FTT) monomers to yield PTBDT-FBT and PTBDT-FTT, which showed high decomposition temperatures (421 and 408 degrees C) and deep-lying HOMO levels (-5.80 and -5.84 eV). The inverted solar cell device using PTBDT-FBT:PC71BM (1: 1 in wt%) blend showed a power conversion efficiency (PCE) of 4.16%, while the device using PTBDT-FTT:PC71BM (1: 2 in wt%) blend showed a PCE of 3.98%.en_US
dc.language.isoen_USen_US
dc.subjectPalladium-catalyzed C-H arylationen_US
dc.subjectTwo-dimensional structureen_US
dc.subjectLadder-type polymeren_US
dc.subjectPolymer solar cellen_US
dc.titleSynthesis of Two-Dimensional Terbenzodithiophene-based Derivative by Palladium-catalyzed C-H Benzannulation and Its Donor-Acceptor Copolymers for Organic Photovoltaicsen_US
dc.typeArticleen_US
dc.identifier.doi10.1002/jccs.201700221en_US
dc.identifier.journalJOURNAL OF THE CHINESE CHEMICAL SOCIETYen_US
dc.citation.volume65en_US
dc.citation.spage133en_US
dc.citation.epage140en_US
dc.contributor.department應用化學系zh_TW
dc.contributor.departmentDepartment of Applied Chemistryen_US
dc.identifier.wosnumberWOS:000423526600015en_US
Appears in Collections:Articles