完整後設資料紀錄
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dc.contributor.authorLin, Meng-Yehen_US
dc.contributor.authorHuang, Tzu-Pingen_US
dc.contributor.authorChin, Chih-Haoen_US
dc.contributor.authorWu, Yu-Jongen_US
dc.date.accessioned2018-08-21T05:53:20Z-
dc.date.available2018-08-21T05:53:20Z-
dc.date.issued2018-02-21en_US
dc.identifier.issn0021-9606en_US
dc.identifier.urihttp://dx.doi.org/10.1063/1.5016869en_US
dc.identifier.urihttp://hdl.handle.net/11536/144569-
dc.description.abstractThe infrared (IR) spectrum of borane(3) anions (BH3-) isolated in solid Ar was recorded; two vibrational modes were observed at 2259.4 and 606.6 cm(-1), which were assigned to the BH2 stretching (nu(3)) and out-of-plane large-amplitude (nu(2)) modes, respectively. These anions were produced by the electron bombardment of an Ar matrix sample containing a small proportion of B2H6 and H-2 during matrix deposition or by the photolysis of single-bridged-B2H5 fi in an Ar matrix with the selected ultraviolet light. The band positions, relative intensity ratios, isotopic splitting pattern, and isotopic shift ratios of the observed IR features of BH3- are generally in good agreement with those predicted by the B2PLYP/aug-cc-pVTZ method.en_US
dc.language.isoen_USen_US
dc.titleFormation and identification of borane radical anions isolated in solid argonen_US
dc.typeArticleen_US
dc.identifier.doi10.1063/1.5016869en_US
dc.identifier.journalJOURNAL OF CHEMICAL PHYSICSen_US
dc.citation.volume148en_US
dc.contributor.department應用化學系zh_TW
dc.contributor.departmentDepartment of Applied Chemistryen_US
dc.identifier.wosnumberWOS:000425808000021en_US
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