Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Sumino, Shuhei | en_US |
dc.contributor.author | Uno, Misae | en_US |
dc.contributor.author | Huang, Hsin-Ju | en_US |
dc.contributor.author | Wu, Yen-Ku | en_US |
dc.contributor.author | Ryu, Ilhyong | en_US |
dc.date.accessioned | 2018-08-21T05:53:21Z | - |
dc.date.available | 2018-08-21T05:53:21Z | - |
dc.date.issued | 2018-02-16 | en_US |
dc.identifier.issn | 1523-7060 | en_US |
dc.identifier.uri | http://dx.doi.org/10.1021/acs.orglett.7b04050 | en_US |
dc.identifier.uri | http://hdl.handle.net/11536/144585 | - |
dc.description.abstract | Alkenylation and allylation of alkyl iodides with alkenyl and allyl sulfones, respectively, took place under Pd/photoirradiation system. The initial alkyl radical, derived from a single electron transfer between Pd(0) and RI, underwent the title transformations. Pd(0) was regenerated through a reductive elimination of PhSO2PdI, which is formed by the combination of the sulfonyl radical and the palladium radical. The addition of water was effective, presumably by pushing the equilibrium through hydrolysis of PhSO2I. | en_US |
dc.language.iso | en_US | en_US |
dc.title | Palladium/Light Induced Radical Alkenylation and Allylation of Alkyl Iodides Using Alkenyl and Allylic Sulfones | en_US |
dc.type | Article | en_US |
dc.identifier.doi | 10.1021/acs.orglett.7b04050 | en_US |
dc.identifier.journal | ORGANIC LETTERS | en_US |
dc.citation.volume | 20 | en_US |
dc.citation.spage | 1078 | en_US |
dc.citation.epage | 1081 | en_US |
dc.contributor.department | 應用化學系 | zh_TW |
dc.contributor.department | Department of Applied Chemistry | en_US |
dc.identifier.wosnumber | WOS:000426013600046 | en_US |
Appears in Collections: | Articles |