標題: Infrared spectra of isotopomers of chloromethylene in solid argon
作者: Lin, Meng-Yeh
Huang, Tzu-Ping
Chin, Chih-Hao
Lee, Yin-Yu
Wu, Yu-Jong
應用化學系
Department of Applied Chemistry
公開日期: 1-三月-2018
摘要: We measured the IR spectra of the solid Ar-trapped chloromethylene (HCCl) prepared by electron bombardment of a CH3Cl/Ar mixture during matrix deposition. Irradiation of matrix samples at 210 nm decreased the intensity of lines corresponding to HCCl, whereas irradiation at 385 nm had an opposite effect. The above behavior allowed an unambiguous identification of all vibrational modes of HCCl, and the obtained assignments were further confirmed by quantum chemical calculations and C-13/H-2 isotopic labeling experiments. (C) 2017 Elsevier Inc. All rights reserved.
URI: http://dx.doi.org/10.1016/j.jms.2017.11.006
http://hdl.handle.net/11536/144624
ISSN: 0022-2852
DOI: 10.1016/j.jms.2017.11.006
期刊: JOURNAL OF MOLECULAR SPECTROSCOPY
Volume: 345
起始頁: 17
結束頁: 21
顯示於類別:期刊論文