標題: | Infrared spectra of isotopomers of chloromethylene in solid argon |
作者: | Lin, Meng-Yeh Huang, Tzu-Ping Chin, Chih-Hao Lee, Yin-Yu Wu, Yu-Jong 應用化學系 Department of Applied Chemistry |
公開日期: | 1-三月-2018 |
摘要: | We measured the IR spectra of the solid Ar-trapped chloromethylene (HCCl) prepared by electron bombardment of a CH3Cl/Ar mixture during matrix deposition. Irradiation of matrix samples at 210 nm decreased the intensity of lines corresponding to HCCl, whereas irradiation at 385 nm had an opposite effect. The above behavior allowed an unambiguous identification of all vibrational modes of HCCl, and the obtained assignments were further confirmed by quantum chemical calculations and C-13/H-2 isotopic labeling experiments. (C) 2017 Elsevier Inc. All rights reserved. |
URI: | http://dx.doi.org/10.1016/j.jms.2017.11.006 http://hdl.handle.net/11536/144624 |
ISSN: | 0022-2852 |
DOI: | 10.1016/j.jms.2017.11.006 |
期刊: | JOURNAL OF MOLECULAR SPECTROSCOPY |
Volume: | 345 |
起始頁: | 17 |
結束頁: | 21 |
顯示於類別: | 期刊論文 |