標題: | UV absorption spectrum of allene radical cations in solid argon |
作者: | Chin, Chih-Hao Lin, Meng-Yeh Huang, Tzu-Ping Wu, Yu-Jong 應用化學系 Department of Applied Chemistry |
關鍵字: | Electronic transition;Matrix isolation;C3H4+;UV absorption spectrum |
公開日期: | 5-五月-2018 |
摘要: | Electron bombardment during deposition of an Ar matrix containing a small proportion of allene generated allene cations. Further irradiation of the matrix sample at 385 nm destroyed the allene cations and formed propyne cations in solid Ar. Both cations were identified according to previously reported IR absorption bands. Using a similar technique, we recorded the ultraviolet absorption spectrum of allene cations in solid Ar. The vibrationally resolved progression recorded in the range of 266-237 nm with intervals of about 800 cm(-1) was assigned to the A E-2 <- X E-2 transition of allene cations, and the broad continuum absorption recorded in the region of 229-214 nm was assigned to their B (2)A(1) <- X E-2 transition. These assignments were made based on the observed photolytic behavior of the progressions and the vertical excitation energies and oscillator strengths calculated using time-dependent density functional theory. (C) 2018 Elsevier B.V. All rights reserved. |
URI: | http://dx.doi.org/10.1016/j.saa.2018.02.028 http://hdl.handle.net/11536/144771 |
ISSN: | 1386-1425 |
DOI: | 10.1016/j.saa.2018.02.028 |
期刊: | SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY |
Volume: | 196 |
起始頁: | 233 |
結束頁: | 237 |
顯示於類別: | 期刊論文 |