Enhancing the magnetic moment of ferrimagnetic NiCo2O4 via ion irradiation driven oxygen vacancies

Abstract

Ion irradiation has emerged as a powerful tool for the efficient control of uniaxial lattice expansion to fine tune and modulate the otherwise inaccessible complex correlated phases in oxide thin-films. We report the fine tuning of the magnetic moment, ferromagnetic-paramagnetic and metal-insulator transition temperatures in the NiCo2O4 inverse-spinel oxide by creating oxygen deficiencies, employing high energy He-ion irradiation. Tailoring of oxygen vacancies and consequently a uniaxial lattice expansion in the out-of-plane direction drives the system toward the increase of the magnetic moment by two-times in magnitude. The magnetic moment increases with the He-ion irradiation fluence up to 2.5 x 10(16)/cm(2) . Our results are corroborated well by spin-polarized electronic structure calculations with density functional theory and X-ray absorption spectroscopic data, which show peak-height change and energy shift of Co-L-2,L-3 and Ni-L-2,L-3 edges driven by the oxygen vacancies. These results demonstrate a new pathway of tailoring oxygen vacancies via He-ion irradiation, useful for designing new functionalities in other complex oxide thin-films. (C) 2018 Author(s).