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dc.contributor.authorLi, Ming-Chiaen_US
dc.contributor.authorOusaka, Naokien_US
dc.contributor.authorWang, Hsiao-Fangen_US
dc.contributor.authorYashima, Eijien_US
dc.contributor.authorHo, Rong-Mingen_US
dc.date.accessioned2018-08-21T05:54:34Z-
dc.date.available2018-08-21T05:54:34Z-
dc.date.issued2017-09-01en_US
dc.identifier.issn2161-1653en_US
dc.identifier.urihttp://dx.doi.org/10.1021/acsmacrolett.7b00493en_US
dc.identifier.urihttp://hdl.handle.net/11536/146129-
dc.description.abstractHere, we show the induced chirality of an achiral chromophoric dye as a joint of polylactide-containing chiral block copolymers (BCPs*) driven by self-assembly, giving the achiral dyes preferentially arranged in a one-handed helical array at the microphase-separated interface. This helical arrangement of the achiral dyes can be "memorized" after hydrolysis of the polylactides in the BCPs* and serves as a chiral template for further chirality induction of different achiral dyes, probably through attractive aromatic pi-pi interactions at the interface, producing nanostructured chiral materials with tunable circular dichroism signals at desired wavelengths.en_US
dc.language.isoen_USen_US
dc.titleChirality Control and Its Memory at Microphase-Separated Interface of Self-Assembled Chiral Block Copolymers for Nanostructured Chiral Materialsen_US
dc.typeArticleen_US
dc.identifier.doi10.1021/acsmacrolett.7b00493en_US
dc.identifier.journalACS MACRO LETTERSen_US
dc.citation.volume6en_US
dc.citation.spage980en_US
dc.citation.epage986en_US
dc.contributor.department生物科技學系zh_TW
dc.contributor.departmentDepartment of Biological Science and Technologyen_US
dc.identifier.wosnumberWOS:000411653600017en_US
Appears in Collections:Articles