Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Kawamoto, Takuji | en_US |
dc.contributor.author | Matsubara, Hiroshi | en_US |
dc.contributor.author | Fukuyama, Takahide | en_US |
dc.contributor.author | Ryu, Ilhyong | en_US |
dc.date.accessioned | 2019-04-02T05:58:34Z | - |
dc.date.available | 2019-04-02T05:58:34Z | - |
dc.date.issued | 2018-09-01 | en_US |
dc.identifier.issn | 0366-7022 | en_US |
dc.identifier.uri | http://dx.doi.org/10.1246/cl.180599 | en_US |
dc.identifier.uri | http://hdl.handle.net/11536/148078 | - |
dc.description.abstract | Aminocarbonylation of aromatic iodides with CO and amines gives aromatic amides under photoirradiation conditions. DFT calculations predict that methylamine adds to benzoyl radical to give a zwitterionic radical, which would afford the product via two pathways: (a) an amine-assisted proton transfer followed by a single electron transfer reaction (SET) with iodobenzene or (b) complexation with iodobenzene and then the SET. | en_US |
dc.language.iso | en_US | en_US |
dc.subject | DFT calculation | en_US |
dc.subject | Radical aminocarbonylation | en_US |
dc.subject | Single electron transfer | en_US |
dc.title | A Theoretical Study on Radical-based Aminocarbonylation of Aryl Iodides | en_US |
dc.type | Article | en_US |
dc.identifier.doi | 10.1246/cl.180599 | en_US |
dc.identifier.journal | CHEMISTRY LETTERS | en_US |
dc.citation.volume | 47 | en_US |
dc.citation.spage | 1169 | en_US |
dc.citation.epage | 1171 | en_US |
dc.contributor.department | 應用化學系 | zh_TW |
dc.contributor.department | Department of Applied Chemistry | en_US |
dc.identifier.wosnumber | WOS:000443399800009 | en_US |
dc.citation.woscount | 1 | en_US |
Appears in Collections: | Articles |