Deuterium-isotope study on the reductive ring opening of benzylidene acetals

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DC 欄位	值	語言
dc.contributor.author	Lee, I-Chi	en_US
dc.contributor.author	Zulueta, Medel Manuel L.	en_US
dc.contributor.author	Shie, Chi-Rung	en_US
dc.contributor.author	Arco, Susan D.	en_US
dc.contributor.author	Hung, Shang-Cheng	en_US
dc.date.accessioned	2014-12-08T15:20:50Z	-
dc.date.available	2014-12-08T15:20:50Z	-
dc.date.issued	2011	en_US
dc.identifier.issn	1477-0520	en_US
dc.identifier.uri	http://hdl.handle.net/11536/14822	-
dc.identifier.uri	http://dx.doi.org/10.1039/c1ob06056b	en_US
dc.description.abstract	Specific deuterated reference compounds were prepared to probe the stereoselectivity of the reductive ring opening of carbohydrate-based benzylidene-type acetals. AlD(3) revealed a retentive stereoselectivity probably through the rare S(N)i (internal nucleophilic substitution) mechanism. An S(N)1-like mechanism occurs in the acid-promoted regioselective BD(3)center dot THF- or Et(3)SiD-reductive ring opening.	en_US
dc.language.iso	en_US	en_US
dc.title	Deuterium-isotope study on the reductive ring opening of benzylidene acetals	en_US
dc.type	Article	en_US
dc.identifier.doi	10.1039/c1ob06056b	en_US
dc.identifier.journal	ORGANIC & BIOMOLECULAR CHEMISTRY	en_US
dc.citation.volume	9	en_US
dc.citation.issue	22	en_US
dc.citation.spage	7655	en_US
dc.citation.epage	7658	en_US
dc.contributor.department	應用化學系	zh_TW
dc.contributor.department	Department of Applied Chemistry	en_US
dc.identifier.wosnumber	WOS:000296203700009	-
dc.citation.woscount	5	-
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