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dc.contributor.authorHiramatsu, Hirotsuguen_US
dc.date.accessioned2019-04-02T05:58:15Z-
dc.date.available2019-04-02T05:58:15Z-
dc.date.issued2019-01-16en_US
dc.identifier.issn0009-2614en_US
dc.identifier.urihttp://dx.doi.org/10.1016/j.cplett.2018.10.064en_US
dc.identifier.urihttp://hdl.handle.net/11536/148538-
dc.description.abstractElectric field effect was investigated on 1-hydroxyacetone (HA) as a model compound of the acyclic form of saccharide moiety employing infrared electroabsorption spectroscopy. We examined the structural tautomerization of the hydroxyacetyl group of HA in detail by monitoring change in IR absorption intensity of the C=O stretching band in the range of 1650-1850 cm(-1). The observed changes in absorbance were analyzed by considering a change in the equilibrium of HA dimer, HA monomer, endiol, and enol forms, as well as the orientational polarization of each tautomer. Conversion from the HA dimer to the enol was detected.en_US
dc.language.isoen_USen_US
dc.subjectElectric field effecten_US
dc.subjectAcyclic structure of carbohydrateen_US
dc.subjectInfrared absorption spectroscopyen_US
dc.titleElectric field effects on 1-hydroxyacetone revealed by IR electroabsorption spectroscopyen_US
dc.typeArticleen_US
dc.identifier.doi10.1016/j.cplett.2018.10.064en_US
dc.identifier.journalCHEMICAL PHYSICS LETTERSen_US
dc.citation.volume714en_US
dc.citation.spage18en_US
dc.citation.epage23en_US
dc.contributor.department交大名義發表zh_TW
dc.contributor.department應用化學系zh_TW
dc.contributor.department應用化學系分子科學碩博班zh_TW
dc.contributor.departmentNational Chiao Tung Universityen_US
dc.contributor.departmentDepartment of Applied Chemistryen_US
dc.contributor.departmentInstitute of Molecular scienceen_US
dc.identifier.wosnumberWOS:000451773500004en_US
dc.citation.woscount0en_US
Appears in Collections:Articles