完整後設資料紀錄
DC 欄位 | 值 | 語言 |
---|---|---|
dc.contributor.author | Hsu, Tze-Gang | en_US |
dc.contributor.author | Chou, Hsiao-Chieh | en_US |
dc.contributor.author | Liang, Ming-Ju | en_US |
dc.contributor.author | Lai, Yu-Ying | en_US |
dc.contributor.author | Cheng, Yen-Ju | en_US |
dc.date.accessioned | 2019-04-02T06:00:59Z | - |
dc.date.available | 2019-04-02T06:00:59Z | - |
dc.date.issued | 2019-01-11 | en_US |
dc.identifier.issn | 1359-7345 | en_US |
dc.identifier.uri | http://dx.doi.org/10.1039/c8cc09485c | en_US |
dc.identifier.uri | http://hdl.handle.net/11536/148673 | - |
dc.description.abstract | Angular-shaped dialkyltetracenedithiophenes (aTDTs) undergo [4+4] photodimerization in solution to form a butterfly-shaped skeleton. This reaction proceeds in a regio- and stereo-selective manner, forming only a single planosymmetric syn-[2,2]-daTDT out of six possible products. The photocycloaddition of aTDTs can take place topochemically in the thin-film state while maintaining regio- and stereo-selectivity. Stronger aliphatic dispersion forces and - interactions play important roles in forming the eclipsed dimeric complex that leads to the syn-[2,2]-daTDT isomer. | en_US |
dc.language.iso | en_US | en_US |
dc.title | Regio- and stereo-selective [4+4] photodimerization of angular-shaped dialkyltetracenedithiophene | en_US |
dc.type | Article | en_US |
dc.identifier.doi | 10.1039/c8cc09485c | en_US |
dc.identifier.journal | CHEMICAL COMMUNICATIONS | en_US |
dc.citation.volume | 55 | en_US |
dc.citation.spage | 381 | en_US |
dc.citation.epage | 384 | en_US |
dc.contributor.department | 應用化學系 | zh_TW |
dc.contributor.department | Department of Applied Chemistry | en_US |
dc.identifier.wosnumber | WOS:000454919600026 | en_US |
dc.citation.woscount | 0 | en_US |
顯示於類別: | 期刊論文 |