Photochemistry of acetone in the presence of exocyclic olefins: An unexpected competition between the photo-Conia and Paterno-Buchi reactions

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DC Field	Value	Language
dc.contributor.author	Chung, WS	en_US
dc.contributor.author	Ho, CC	en_US
dc.date.accessioned	2019-04-02T06:00:31Z	-
dc.date.available	2019-04-02T06:00:31Z	-
dc.date.issued	1997-02-07	en_US
dc.identifier.issn	1359-7345	en_US
dc.identifier.uri	http://dx.doi.org/10.1039/a607415d	en_US
dc.identifier.uri	http://hdl.handle.net/11536/149439	-
dc.description.abstract	When irradiated in the presence of several exocyclic olefins, acetone undergoes homoalkylation with the olefins to form a series of 4-cycloalkylbutan-2-ones (with quantum yields of 0.14 +/- 0.01) rather than exhibiting the expected Paterno-Buchi reaction; in contrast, the photolysis of perdeuteriated acetone gave both types of products.	en_US
dc.language.iso	en_US	en_US
dc.title	Photochemistry of acetone in the presence of exocyclic olefins: An unexpected competition between the photo-Conia and Paterno-Buchi reactions	en_US
dc.type	Article	en_US
dc.identifier.doi	10.1039/a607415d	en_US
dc.identifier.journal	CHEMICAL COMMUNICATIONS	en_US
dc.citation.spage	317	en_US
dc.citation.epage	318	en_US
dc.contributor.department	應用化學系	zh_TW
dc.contributor.department	Department of Applied Chemistry	en_US
dc.identifier.wosnumber	WOS:A1997WJ50700034	en_US
dc.citation.woscount	3	en_US
Appears in Collections:	Articles