標題: | A novel hydride rearrangement of the acetal group of tetraacetal tetraoxa-cages mediated by Lewis acids |
作者: | Wu, HJ Chern, JH 應用化學系 Department of Applied Chemistry |
公開日期: | 21-三月-1997 |
摘要: | Treatment of tetraoxa-cages 1a-f with Lewis acids such as TlC4, AlCl3, BF3 . OEt(2) and MeSO(3)H in dichloromethane at 25 degrees C gives the rearrangement products 2a-f in 90% yields regioselectively and stereoselectively; a novel hydride rearrangement of the acetal group of tetraacetal tetraoxa-cages mediated by Lewis acids. |
URI: | http://dx.doi.org/10.1039/a607403k http://hdl.handle.net/11536/149476 |
ISSN: | 1359-7345 |
DOI: | 10.1039/a607403k |
期刊: | CHEMICAL COMMUNICATIONS |
起始頁: | 547 |
結束頁: | 548 |
顯示於類別: | 期刊論文 |