Synthesis and luminescence properties of Eu3+, Ce3+ and Tb3+-activated Sr3La2(BO3)(4) under UV excitation

Abstract

The spectroscopic properties in UV-excitable range for the phosphors of Sr3La2(BO3)(4):RE3+ (RE3+ = Eu3+, Ce3+, Tb3+) were investigated. The phosphors were synthesized by conventional solid-state reactions. The photoluminescence (PL) spectra and commission international de l'Eclairage (CIE) coordinates of Sr3La2(BO3)4:RE 31 were investigated. The f-d transitions of Eu3+, Ce3+ and Tb3+ in the host lattices are assumed and corroborated. The PL and PL excitation (PLE) spectra indicate that the main emission wavelength of Sr3La2(BO3)(4):Eu3+ is 611 nm, and Sr3La2(BO3)(4):Ce3+ shows dominating emission peak at 425 nm, while Sr3La2(BO3)(4):Tb3+ displays green emission at 487, 542, 582 and 620 nm. These phosphors were prepared by simple solid-state reaction at 1000 degrees C. There are lower reactive temperature and more convenient than commercial phosphors. The Sr3La2(BO3)(4):Tb3+ applied to cold cathode fluorescent lamp was found to emit green light and have a major peak wavelength at around 542 nm. These phosphors may provide a new kind of luminescent materials under ultraviolet excitation. Crown Copyright (C) 2009 Published by Elsevier B.V. All rights reserved.