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dc.contributor.authorHan, Hui-Lingen_US
dc.contributor.authorFu, Lungen_US
dc.contributor.authorLee, Yuan-Pernen_US
dc.date.accessioned2019-04-02T05:58:01Z-
dc.date.available2019-04-02T05:58:01Z-
dc.date.issued2011-10-17en_US
dc.identifier.issn0009-2614en_US
dc.identifier.urihttp://dx.doi.org/10.1016/j.cplett.2011.06.090en_US
dc.identifier.urihttp://hdl.handle.net/11536/150406-
dc.description.abstractWe present a detailed spectral study of the atmospherically important methylthio (CH3S) radical demonstrating the advantage of IR-VUV photoionization for vibrational spectroscopy of free radicals due to its mass selectivity. Photolysis of CH3SH produced CH3S radicals that were ionized with (1 + 1) IR-VUV photoionization and detected with the time-of-flight technique. The IR spectrum of CH3S was obtained in the range 2790-3270 cm (1). Absorptions features near 2819 and 2904 cm (1) are assigned to nu(1) and nu(4) modes of CH3S, respectively, and those near 2978 and 3241 cm (1) are tentatively assigned as combination transitions 3(1)5(1)6(1)(e) and 3(1)5(1)6(1)(a), respectively, from the ground vibrational state. (C) 2011 Elsevier B.V. All rights reserved.en_US
dc.language.isoen_USen_US
dc.titleInfrared spectrum of mass-selected CH3S radicals investigated with infrared plus vacuum ultraviolet photoionizationen_US
dc.typeArticleen_US
dc.identifier.doi10.1016/j.cplett.2011.06.090en_US
dc.identifier.journalCHEMICAL PHYSICS LETTERSen_US
dc.citation.volume515en_US
dc.citation.spage1en_US
dc.citation.epage6en_US
dc.contributor.department應用化學系zh_TW
dc.contributor.department應用化學系分子科學碩博班zh_TW
dc.contributor.departmentDepartment of Applied Chemistryen_US
dc.contributor.departmentInstitute of Molecular scienceen_US
dc.identifier.wosnumberWOS:000296551300001en_US
dc.citation.woscount12en_US
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