標題: | Pure rotational spectrum of cis-OSOO |
作者: | Nakajima, Masakazu Endo, Yasuki 應用化學系 Department of Applied Chemistry |
關鍵字: | Pure rotational transitions;cis-OSOO;Molecular structure;Discharge plasma |
公開日期: | 16-Jun-2019 |
摘要: | Pure rotational transitions of cis-OSOO are identified in a discharge plasma of a SO2 and O-2 gaseous mixture by Fourier-transform microwave (FTMW) and FTMW-MW double-resonance spectroscopy. Both a- and b-type transitions are observed for this molecule, and the rotational and centrifugal distortion constants are precisely determined from the observed line positions. The inertial defect calculated from the determined rotational constants indicates that the cis-OSOO molecule has a planar equilibrium geometry in the ground vibronic state. |
URI: | http://dx.doi.org/10.1016/j.cplett.2019.03.061 http://hdl.handle.net/11536/151916 |
ISSN: | 0009-2614 |
DOI: | 10.1016/j.cplett.2019.03.061 |
期刊: | CHEMICAL PHYSICS LETTERS |
Volume: | 725 |
起始頁: | 14 |
結束頁: | 17 |
Appears in Collections: | Articles |