標題: Pure rotational spectrum of cis-OSOO
作者: Nakajima, Masakazu
Endo, Yasuki
應用化學系
Department of Applied Chemistry
關鍵字: Pure rotational transitions;cis-OSOO;Molecular structure;Discharge plasma
公開日期: 16-Jun-2019
摘要: Pure rotational transitions of cis-OSOO are identified in a discharge plasma of a SO2 and O-2 gaseous mixture by Fourier-transform microwave (FTMW) and FTMW-MW double-resonance spectroscopy. Both a- and b-type transitions are observed for this molecule, and the rotational and centrifugal distortion constants are precisely determined from the observed line positions. The inertial defect calculated from the determined rotational constants indicates that the cis-OSOO molecule has a planar equilibrium geometry in the ground vibronic state.
URI: http://dx.doi.org/10.1016/j.cplett.2019.03.061
http://hdl.handle.net/11536/151916
ISSN: 0009-2614
DOI: 10.1016/j.cplett.2019.03.061
期刊: CHEMICAL PHYSICS LETTERS
Volume: 725
起始頁: 14
結束頁: 17
Appears in Collections:Articles