Pure rotational spectrum of cis-OSOO

doi:10.1016/j.cplett.2019.03.061

Title:	Pure rotational spectrum of cis-OSOO
Authors:	Nakajima, Masakazu Endo, Yasuki 應用化學系 Department of Applied Chemistry
Keywords:	Pure rotational transitions;cis-OSOO;Molecular structure;Discharge plasma
Issue Date:	16-Jun-2019
Abstract:	Pure rotational transitions of cis-OSOO are identified in a discharge plasma of a SO2 and O-2 gaseous mixture by Fourier-transform microwave (FTMW) and FTMW-MW double-resonance spectroscopy. Both a- and b-type transitions are observed for this molecule, and the rotational and centrifugal distortion constants are precisely determined from the observed line positions. The inertial defect calculated from the determined rotational constants indicates that the cis-OSOO molecule has a planar equilibrium geometry in the ground vibronic state.
URI:	http://dx.doi.org/10.1016/j.cplett.2019.03.061 http://hdl.handle.net/11536/151916
ISSN:	0009-2614
DOI:	10.1016/j.cplett.2019.03.061
Journal:	CHEMICAL PHYSICS LETTERS
Volume:	725
Begin Page:	14
End Page:	17
Appears in Collections:	Articles