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dc.contributor.authorKao, Shih-Chiehen_US
dc.contributor.authorLin, Yi-Chingen_US
dc.contributor.authorRyu, Ilhyongen_US
dc.contributor.authorWu, Yen-Kuen_US
dc.date.accessioned2019-08-02T02:15:34Z-
dc.date.available2019-08-02T02:15:34Z-
dc.date.issued1970-01-01en_US
dc.identifier.issn1615-4150en_US
dc.identifier.urihttp://dx.doi.org/10.1002/adsc.201900287en_US
dc.identifier.urihttp://hdl.handle.net/11536/152246-
dc.description.abstractDescribed is a tetrabutylammonium fluoride-mediated hydroxyalkylation reaction of phenols with cyclic carbonates. This operationally simple method enables the synthesis of a variety of aryl beta-hydroxyethyl ethers in good to excellent yields with a very small amount of catalyst loading (0.1-1 mol%). Of particular note is the efficient conversion of aromatic diols and phloroglucinol to the corresponding bis- and tris-hydroxyethylated products. To further showcase the versatility of this protocol, guaifenesin was prepared with a single step by the condensation of guaiacol and glycerol carbonate. We also developed a flow ethoxylation process permitting the continuous synthesis of multiflorol.en_US
dc.language.isoen_USen_US
dc.subjectphenolsen_US
dc.subjectethylene carbonateen_US
dc.subjectethoxylationen_US
dc.subjectTBAFen_US
dc.subject2-phenoxyethanolen_US
dc.subjectflow chemistryen_US
dc.titleRevisiting Hydroxyalkylation of Phenols with Cyclic Carbonatesen_US
dc.typeArticleen_US
dc.identifier.doi10.1002/adsc.201900287en_US
dc.identifier.journalADVANCED SYNTHESIS & CATALYSISen_US
dc.citation.spage0en_US
dc.citation.epage0en_US
dc.contributor.department應用化學系zh_TW
dc.contributor.departmentDepartment of Applied Chemistryen_US
dc.identifier.wosnumberWOS:000474102500001en_US
dc.citation.woscount0en_US
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