標題: | Vicinal difunctionalization of alkenes by four-component radical cascade reaction of xanthogenates, alkenes, CO, and sulfonyl oxime ethers |
作者: | Sumino, Shuhei Fukuyama, Takahide Sasano, Mika Ryu, Ilhyong Jacquet, Antoine Robert, Frederic Landais, Yannick 應用化學系 Department of Applied Chemistry |
關鍵字: | CO;multicomponent reaction;radicals;sulfonyl oxime ethers;xanthogenates |
公開日期: | 31-七月-2019 |
摘要: | Four-component coupling reactions between xanthogenates, alkenes, CO, and sulfonyl oxime ethers were studied. In the presence of hexabutylditin, working as a propagating radical reagent, the chain reaction proceeds, as expected, taking into account reagents polarities, affording the corresponding functionalized alpha-keto oximes. Although yields are modest, this rare one-pot four-component process is easy to carry out and the resulting compounds, bearing multiple functionalities, have the potential for further elaboration. |
URI: | http://dx.doi.org/10.3762/bjoc.15.176 http://hdl.handle.net/11536/152696 |
ISSN: | 1860-5397 |
DOI: | 10.3762/bjoc.15.176 |
期刊: | BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY |
Volume: | 15 |
起始頁: | 1822 |
結束頁: | 1828 |
顯示於類別: | 期刊論文 |