標題: Vicinal difunctionalization of alkenes by four-component radical cascade reaction of xanthogenates, alkenes, CO, and sulfonyl oxime ethers
作者: Sumino, Shuhei
Fukuyama, Takahide
Sasano, Mika
Ryu, Ilhyong
Jacquet, Antoine
Robert, Frederic
Landais, Yannick
應用化學系
Department of Applied Chemistry
關鍵字: CO;multicomponent reaction;radicals;sulfonyl oxime ethers;xanthogenates
公開日期: 31-七月-2019
摘要: Four-component coupling reactions between xanthogenates, alkenes, CO, and sulfonyl oxime ethers were studied. In the presence of hexabutylditin, working as a propagating radical reagent, the chain reaction proceeds, as expected, taking into account reagents polarities, affording the corresponding functionalized alpha-keto oximes. Although yields are modest, this rare one-pot four-component process is easy to carry out and the resulting compounds, bearing multiple functionalities, have the potential for further elaboration.
URI: http://dx.doi.org/10.3762/bjoc.15.176
http://hdl.handle.net/11536/152696
ISSN: 1860-5397
DOI: 10.3762/bjoc.15.176
期刊: BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY
Volume: 15
起始頁: 1822
結束頁: 1828
顯示於類別:期刊論文