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dc.contributor.authorIritani, Koheien_US
dc.contributor.authorKaneko, Kyoheien_US
dc.contributor.authorTahara, Kazukunien_US
dc.contributor.authorDe Feyter, Stevenen_US
dc.contributor.authorTobe, Yoshitoen_US
dc.date.accessioned2020-05-05T00:01:31Z-
dc.date.available2020-05-05T00:01:31Z-
dc.date.issued1970-01-01en_US
dc.identifier.issn2199-692Xen_US
dc.identifier.urihttp://dx.doi.org/10.1002/cnma.201900733en_US
dc.identifier.urihttp://hdl.handle.net/11536/153958-
dc.description.abstractAn approach to synthesize a two-dimensional polymer (2DP) using a preorganized host-guest network at the liquid/solid interface is presented. As a host network, we used a self-assembled monolayer of a dehydrobenzo[12]annulene derivative having aminophenyl groups at three alkoxy chain ends and, as a guest, a hexakis(phenylethynyl)benzene derivative having six formyl groups, aiming to connect the host to the guest embedded in the host matrix by imine bond formation. STM observations of host-guest mixtures with trifluoroacetic acid at the 1-phenyloctane/highly oriented pyrolytic graphite interface revealed that the guest was observed as a spoke-like feature in the nanowells. Based on the STM image analysis, short distances between the diagonal phenyl groups in the nanowells are detected, indicating that the imine bonds are formed. However, the small abundance and random distribution of the short phenyl-phenyl distance indicate that the periodically ordered 2DP structure is not formed, probably because the network cannot tolerate the structural change due to partial bond formation.en_US
dc.language.isoen_USen_US
dc.subjectHost-guest systemsen_US
dc.subjectInterfacesen_US
dc.subjectPolymerizationen_US
dc.subjectScanning probe microscopyen_US
dc.subjectSelf-assemblyen_US
dc.titleAn Approach to the Synthesis of a Two-Dimensional Polymer Using a Preorganized Host-Guest Network by Self-Assembly at the Liquid/Solid Interfaceen_US
dc.typeArticleen_US
dc.identifier.doi10.1002/cnma.201900733en_US
dc.identifier.journalCHEMNANOMATen_US
dc.citation.spage0en_US
dc.citation.epage0en_US
dc.contributor.department應用化學系zh_TW
dc.contributor.departmentDepartment of Applied Chemistryen_US
dc.identifier.wosnumberWOS:000517433500001en_US
dc.citation.woscount0en_US
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