Direct observation of denitrogenation process of 2,3-diazabicyclo[2.2.1]hept-2-ene (DBH) derivatives, using a visible 5-fs pulse laser

標題:	Direct observation of denitrogenation process of 2,3-diazabicyclo[2.2.1]hept-2-ene (DBH) derivatives, using a visible 5-fs pulse laser
作者:	Abe, Manabu Iwakura, Izumi Yabushita, Atushi Yagi, Shingo Liu, Jun Okamura, Kotaro Kobayashi, Takayoshi 電子物理學系 Department of Electrophysics
公開日期:	27-Feb-2012
摘要:	The mechanism of denitrogenation for 2,3-diazabicyclo[2.2.1]hept-2-ene (DBH) derivatives was investigated using a visible 5-fs pulse laser. The time-dependent wavenumber changes observed in this study revealed that the concerted denitrogenation occurs in the parent DBH. However, a stepwise denitrogenation mechanism was found for the 7,7-diethoxy-substituted DBH derivative. (C) 2012 Elsevier B. V. All rights reserved.
URI:	http://dx.doi.org/10.1016/j.cplett.2012.01.024 http://hdl.handle.net/11536/15621
ISSN:	0009-2614
DOI:	10.1016/j.cplett.2012.01.024
期刊:	CHEMICAL PHYSICS LETTERS
Volume:	527
Issue:
起始頁:	79
結束頁:	83
Appears in Collections:	Articles

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