標題: Observation of Raman Optical Activity by Heterodyne-Detected Polarization-Resolved Coherent Anti-Stokes Raman Scattering
作者: Hiramatsu, Kotaro
Okuno, Masanari
Kano, Hideaki
Leproux, Philippe
Couderc, Vincent
Hamaguchi, Hiro-o
應用化學系
應用化學系分子科學碩博班
Department of Applied Chemistry
Institute of Molecular science
公開日期: 24-八月-2012
摘要: We report the first observation of Raman optical activity (ROA) by coherent anti-Stokes Raman scattering. Thanks to the more freedom of polarization configurations in coherent anti-Stokes Raman scattering than in spontaneous Raman spectroscopy, the contrast ratio of the chiral signal to the achiral background has been improved markedly. For (-)-beta-pinene, it is 2 orders of magnitude better than that in the reported spontaneous ROA measurement. This is also the first measurement of ROA signal using a pulsed laser source.
URI: http://dx.doi.org/10.1103/PhysRevLett.109.083901
http://hdl.handle.net/11536/16726
ISSN: 0031-9007
DOI: 10.1103/PhysRevLett.109.083901
期刊: PHYSICAL REVIEW LETTERS
Volume: 109
Issue: 8
起始頁: 0
結束頁: 0
顯示於類別:期刊論文


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