Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Ito, Syoji | en_US |
dc.contributor.author | Tanaka, Yoshito | en_US |
dc.contributor.author | Yoshikawa, Hiroyuki | en_US |
dc.contributor.author | Ishibashi, Yukihide | en_US |
dc.contributor.author | Miyasaka, Hiroshi | en_US |
dc.contributor.author | Masuhara, Hiroshi | en_US |
dc.date.accessioned | 2014-12-08T15:26:50Z | - |
dc.date.available | 2014-12-08T15:26:50Z | - |
dc.date.issued | 2011-09-21 | en_US |
dc.identifier.issn | 0002-7863 | en_US |
dc.identifier.uri | http://dx.doi.org/10.1021/ja200737j | en_US |
dc.identifier.uri | http://hdl.handle.net/11536/19093 | - |
dc.description.abstract | Controlling chemical reactions within a small space is a significant issue in chemistry, and methods to induce reactions within a desired position have various potential applications. Here we demonstrate localized, efficient photopolymerization by radiation pressure. We induced a one-photon UV polymerization of liquid acrylate solutions in the optical-trapping potential of a focused near-IR (NIR) laser beam, leading to the confinement of solidification to a minute space with dimensions smaller or equal to one-fifth of the wavelength of the NIR laser. Our approach can produce solidification volumes smaller than those achievable with conventional one-photon polymerization, thus enabling the production of tiny polymeric structures that are smaller than the diffraction limit of the trapping light. This is the first demonstration of a radiation pressure effect on a photochemical reaction. | en_US |
dc.language.iso | en_US | en_US |
dc.title | Confinement of Photopolymerization and Solidification with Radiation Pressure | en_US |
dc.type | Article | en_US |
dc.identifier.doi | 10.1021/ja200737j | en_US |
dc.identifier.journal | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | en_US |
dc.citation.volume | 133 | en_US |
dc.citation.issue | 37 | en_US |
dc.citation.spage | 14472 | en_US |
dc.citation.epage | 14475 | en_US |
dc.contributor.department | 應用化學系 | zh_TW |
dc.contributor.department | 應用化學系分子科學碩博班 | zh_TW |
dc.contributor.department | Department of Applied Chemistry | en_US |
dc.contributor.department | Institute of Molecular science | en_US |
dc.identifier.wosnumber | WOS:000295148100002 | - |
dc.citation.woscount | 8 | - |
Appears in Collections: | Articles |
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