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dc.contributor.authorLin, Zong-Sianen_US
dc.contributor.authorChiou, Tzung-Wenen_US
dc.contributor.authorLiu, Kuan-Yuen_US
dc.contributor.authorHsieh, Chang-Chihen_US
dc.contributor.authorYu, Jen-Shiang K.en_US
dc.contributor.authorLiaw, Wen-Fengen_US
dc.date.accessioned2014-12-08T15:28:15Z-
dc.date.available2014-12-08T15:28:15Z-
dc.date.issued2012-10-01en_US
dc.identifier.issn0020-1669en_US
dc.identifier.urihttp://dx.doi.org/10.1021/ic3018437en_US
dc.identifier.urihttp://hdl.handle.net/11536/20466-
dc.description.abstractNitrosylation of the chelate thiolate-containing dinitrosyliron complex (DNIC) [(S(CH2)(3)S)Fe-(NO)(2)](-) triggers nitric oxide (NO) activation to generate the homoleptic nitrosyl {Fe(NO)(2)}(9) DNIC [Fe(NO)(4)](-) (1) made up of two nitroxyls (or two NO anions) attached to a delocalized {Fe(NO)(2)}(9) motif. The significantly longer N3-O3/N4-O4 [1.380(12) and 1.280(12) angstrom] and Fe1-N3/Fe1-N4 [2.008(11) and 2.045(10) angstrom] bond distances reflect that N3-O3 and N4-O4 of complex 1 may act as the nitroxyl-coordinated ligands. That is, the electronic structure of the DNIC 1 is best described as a {Fe(NO)(2)}(9) motif coordinated by two nitroxyl (NO-) ligands.en_US
dc.language.isoen_USen_US
dc.titleA Dinitrosyliron Complex within the Homoleptic Fe(NO)(4) Anion: NO as Nitroxyl and Nitrosyl Ligands within a Single Structureen_US
dc.typeArticleen_US
dc.identifier.doi10.1021/ic3018437en_US
dc.identifier.journalINORGANIC CHEMISTRYen_US
dc.citation.volume51en_US
dc.citation.issue19en_US
dc.citation.spage10092en_US
dc.citation.epage10094en_US
dc.contributor.department生物科技學系zh_TW
dc.contributor.department生物資訊及系統生物研究所zh_TW
dc.contributor.departmentDepartment of Biological Science and Technologyen_US
dc.contributor.departmentInstitude of Bioinformatics and Systems Biologyen_US
dc.identifier.wosnumberWOS:000309298200010-
dc.citation.woscount8-
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