標題: A Novel Tunable Green- to Yellow-Emitting beta-YFS:Ce(3+) Phosphor for Solid-State Lighting
作者: Wu, Yun-Chen
Wang, De-Yin
Chen, Teng-Ming
Lee, Chi-Shen
Chen, Kuo-Ju
Kuo, Hao-chung
應用化學系
應用化學系分子科學碩博班
光電工程學系
Department of Applied Chemistry
Institute of Molecular science
Department of Photonics
公開日期: 1-八月-2011
摘要: A Ce(3+)-activated fluorosulfide phosphor (beta-YFS: Ce(3+)) was synthesized by solid-state reaction in a sealed tube. The crystal structure has been refined from the XRD profiles and there are two different crystallographic rare earth sites, namely, Y(1) and Y(2), where the Ce(3+) ions occupied. The emission band with a maximum at 495 nm of beta-Y(0.99)Ce(0.01) FS phosphor was characterized by the 4f-5d transitions of Ce(3+) ion. With increasing Ce(3+) concentration, the emission variations were observed from 495 to 547 nm. When beta-YFS:Ce(3+) phosphors were utilized to incorporate with n-UV/blue chip, greenish-white light with color rendering index of 65-77 were obtained. The results indicate that the tunable green- to yellow-emitting beta-YFS:Ce(3+) can serve as a potential phosphor for incorporation in fabrication for solid-state lighting. The preparation, spectroscopic characterization, quantum efficiency, thermal-quenching behavior, and related LED device data are also presented.
URI: http://dx.doi.org/10.1021/am2006965
http://hdl.handle.net/11536/20738
ISSN: 1944-8244
DOI: 10.1021/am2006965
期刊: ACS APPLIED MATERIALS & INTERFACES
Volume: 3
Issue: 8
起始頁: 3195
結束頁: 3199
顯示於類別:期刊論文