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dc.contributor.authorChen, Wen-Chingen_US
dc.contributor.authorHsu, Yu-Chenen_US
dc.contributor.authorLee, Ching-Yuen_US
dc.contributor.authorYap, Glenn P. A.en_US
dc.contributor.authorOng, Tiow-Ganen_US
dc.date.accessioned2014-12-08T15:30:42Z-
dc.date.available2014-12-08T15:30:42Z-
dc.date.issued2013-04-22en_US
dc.identifier.issn0276-7333en_US
dc.identifier.urihttp://dx.doi.org/10.1021/om400139sen_US
dc.identifier.urihttp://hdl.handle.net/11536/21930-
dc.description.abstractThe paper describes the synthetic development of Bertrand-type acyclic carbodicarbene scaffolds derived from an unsymmetrical bis(benzimidazol-2-yl)methane bearing two sterically demanding pendant arms, isopropyl (6a) or cyclohexyl (6b). X-ray crystallographic analysis shows that the impact of these pendant arms on the overall structural parameters of carbodicarbenes is minimal. The chemical reactivity of the carbodicarbenes was evaluated with iodomethane to afford compound 7, illustrating its nudeophilic properties. Finally, experiments were also undertaken to investigate the coordination ability of carbodicarbene toward the formation of rhodium carbonyl (10) and palladium allyl complexes (11). The crystal structures of the metal complexes have been determined, revealing that their metal-carbene distances are elongated only slightly, this fact was rationalized on the basis of geometrical steric considerations with regard to the ligand.en_US
dc.language.isoen_USen_US
dc.titleSynthetic Modification of Acyclic Bent Allenes (Carbodicarbenes) and Further Studies on Their Structural Implications and Reactivitiesen_US
dc.typeArticleen_US
dc.identifier.doi10.1021/om400139sen_US
dc.identifier.journalORGANOMETALLICSen_US
dc.citation.volume32en_US
dc.citation.issue8en_US
dc.citation.spage2435en_US
dc.citation.epage2442en_US
dc.contributor.department應用化學系zh_TW
dc.contributor.departmentDepartment of Applied Chemistryen_US
dc.identifier.wosnumberWOS:000318060400018-
dc.citation.woscount7-
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