標題: Element-specific study of the coupled magneto-structural and magneto-electronic properties of CoNi nanoarrays
作者: Yang, Chao-Yao
Tseng, Yuan-Chieh
Lin, Hong-Ji
材料科學與工程學系
Department of Materials Science and Engineering
關鍵字: Nanoarrays;CoNi;XMCD;Electroless;Magneto-crystalline anisotropy
公開日期: 1-Apr-2013
摘要: The magneto-structural (MS) and magneto-electronic (ME) effects, as well as their coupling relationship, were investigated in electroless-plated (EL) Co0.5Ni0.5 arrays treated by post N-2 annealing and in situ field plating. Separately and combined, these two treatments have been widely employed to improve the properties of magnetic nanostructures. This work aimed to discriminate between treatments with respect to electronic and structural properties, and magnetic degrees of freedom of Co0.5Ni0.5 nanostructures. The field-plated sample exhibited a strong MS-ME coupling due to magneto-crystalline anisotropy (MCA), arising from a FCC (111) preferred orientation with lattice planes stacking orthogonally to the long axial direction of the arrays. A large coercivity was observed in this structure, arising from high magnetic stability. X-ray magnetic circular dichroism revealed that magnetization was enhanced primarily by Co magnetism, while the field-plated sample underwent a MS/ME transition with corresponding increase of the plating field. Conversely, the heat-treated sample comprised isotropically oriented nanocrystals approximately 20 +/- 3 nm in diameter, coated with an oxidation layer (approximately 5 +/- 2 nm thick). The absence of MCA in these samples ensured a weak MS-ME coupling. Although the Ni magnetization of heat-treated samples remained close to that of the field-plated sample, the Co constituent exhibited CoO and Co3O4 phases in addition to the metallic state. By contrast, the Co constituent of the field-plated sample was mainly metallic. The lack of MCA, combined with a complex Co magnetic state, appears responsible for the divergent macroscopic magnetic behaviors of the heat-treated and the field-plated samples. By isolating changes in local magnetic moments of Ni and Co, we gained a fundamental understanding of the effects of post-N-2 annealing and field plating on CoNi. Such knowledge may assist researches in improving the magnetic properties of bimetallic nanostructures.
URI: http://dx.doi.org/10.1007/s11051-013-1542-4
http://hdl.handle.net/11536/22396
ISSN: 1388-0764
DOI: 10.1007/s11051-013-1542-4
期刊: JOURNAL OF NANOPARTICLE RESEARCH
Volume: 15
Issue: 4
結束頁: 
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