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dc.contributor.authorWang, Qiaoqiaoen_US
dc.contributor.authorWu, Dien_US
dc.contributor.authorJin, Mingxingen_US
dc.contributor.authorLiu, Fuchunen_US
dc.contributor.authorHu, Feifeien_US
dc.contributor.authorCheng, Xihuien_US
dc.contributor.authorLiu, Hangen_US
dc.contributor.authorHu, Zhanen_US
dc.contributor.authorDing, Dajunen_US
dc.contributor.authorMineo, H.en_US
dc.contributor.authorDyakov, Y. A.en_US
dc.contributor.authorMebel, A. M.en_US
dc.contributor.authorChao, S. D.en_US
dc.contributor.authorLin, S. H.en_US
dc.date.accessioned2014-12-08T15:31:45Z-
dc.date.available2014-12-08T15:31:45Z-
dc.date.issued2008-11-28en_US
dc.identifier.issn0021-9606en_US
dc.identifier.urihttp://dx.doi.org/10.1063/1.3023034en_US
dc.identifier.urihttp://hdl.handle.net/11536/22465-
dc.description.abstractThe 3p sigma(u)D (3)Sigma(+)(u) Rydberg state of N(2) is studied experimentally using two high-resolution spectroscopic techniques. First, the forbidden D (3)Sigma(+)(u)-X (1)Sigma(+)(g) transition is observed for the first time via the (0,0) band of (14)N(2) and the (1,0) band of (15)N(2), using 1 extreme-ultraviolet +1 ultraviolet two-photon-ionization laser spectroscopy. Second, the Rydberg-Rydberg transition D (3)Sigma(+)(u)-E (3)Sigma(+)(g) is studied using near-infrared diode-laser photoabsorption spectroscopy, thus extending the previous measurements of Kanamori [J. Chem. Phys. 95, 80 (1991)], to higher transition energies, and thereby revealing the (2,2) and (3,3) bands. The combined results show that the D(v=0-3) levels exhibit rapidly increasing rotational predissociation as v increases, spanning nearly four orders of magnitude. The D-state level structure and rotational predissociation signature are explained by means of a coupled-channels model which considers the electrostatically coupled (3)Pi(u) Rydberg-valence manifold, together with a pure-precession L-uncoupling rotational interaction between the 3p sigma(u)D (3)Sigma(+)(u) and 3p pi(u)G (3)Pi(u) Rydberg p-complex components.en_US
dc.language.isoen_USen_US
dc.titleStructure and predissociation of the 3p sigma(u)D (3)Sigma(+)(u) Rydberg state of N(2): First extreme-ultraviolet and new near-infrared observations, with coupled-channels analysisen_US
dc.typeArticleen_US
dc.identifier.doi10.1063/1.3023034en_US
dc.identifier.journalJOURNAL OF CHEMICAL PHYSICSen_US
dc.citation.volume129en_US
dc.citation.issue20en_US
dc.citation.spage1en_US
dc.citation.epage15en_US
dc.contributor.department應用化學系zh_TW
dc.contributor.departmentDepartment of Applied Chemistryen_US
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