Title: Cathodic deposition of TiO2 thin films with supercritical CO2 emulsified electrolyte
Authors: Chang, Tso-Fu Mark
Lin, Wei-Hao
Hsu, Yung-Jung
Chen, Chun-Yi
Sato, Tatsuo
Sone, Masato
材料科學與工程學系
Department of Materials Science and Engineering
Keywords: TiO2;Cathodic deposition;Supercritical CO2;Morphology;Grain size
Issue Date: 1-Aug-2013
Abstract: TiO2 thin films were fabricated by cathodic deposition with a supercritical CO2 (sc-CO2) emulsified TiCl3 + NaNO3 electrolyte. Morphology and average grain size were evaluated by SEM, TEM and XRD. SEM micrographs showed that the TiO2 films fabricated by TiCl3 + NaNO3 electrolyte were porous, and the films were composed of particles and aggregates of the particles. Also, size of the particles increased when the sc-CO2 emulsified electrolyte was used. Average grain size of the TiO2 films was calculated using Scherrer equation. The average grain size was found to increase when the sc-CO2 emulsified electrolyte was used. In addition, both particle sizes observed from SEM and average grain size calculated using Scherrer equation were found to increase when pressure was increased from atmospheric pressure to 20 MPa. (c) 2013 Elsevier B.V. All rights reserved.
URI: http://dx.doi.org/10.1016/j.elecom.2013.04.025
http://hdl.handle.net/11536/22571
ISSN: 1388-2481
DOI: 10.1016/j.elecom.2013.04.025
Journal: ELECTROCHEMISTRY COMMUNICATIONS
Volume: 33
Issue: 
Begin Page: 68
End Page: 71
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